SIR,

THO’ iron is universally allowed to be one of the most powerful

medicines now in use, yet many physicians observing, that the _fæces_

of patients, who used it either in a metallic or saline form, were

tinged of a black colour, have been led to think, that, in a metallic

state, it could not be reduced into particles fine enough to be

received by the lacteal vessels; and if taken in a saline form, that

it underwent a precipitation in the intestines, by which, being

reduced to an earth or calx, it was in like manner rendered incapable

of making its way into the blood. But the accurate experiments, with

which Signor Menghini has favoured the public in the Memoirs of the

Bononian Academy[34], sufficiently prove, that the ore and filings of

iron, finely levigated, enter the blood in considerable quantity; as

does also the _crocus_, _calx_, or earthy part of the metal, tho’ in

less proportion than the two former, which were found to act with a

violent _stimulus_ on the vessels, and to have dissolved and broke the

_crasis_ of the blood of different animals, that had used them for some

weeks in large doses mixed with their ordinary food. Tho’ it must be

allowed, that these experiments are very curious, yet the subject seems

to require a further inquiry, viz. _Whether iron is capable of entering

the blood in a state of solution, or under a saline form_: for, from

the violent _stimulus_, as well as from the dissolution of the blood,

and other symptoms brought on by the use of the ore and filings, these

substances (not being properly dissolved) appear to have acted in a

manner so grossly mechanical, that, whatever Signor Menghini may think,

very little is to be concluded from them, with regard to the action of

iron on the human body, in such cases, as indicate its use, and where a

rational physician would think proper to prescribe it as a medicine.

Having read Signor Menghini’s memoir, I recollected, that in the year

1753 I had, with the assistance of two friends, made the following

experiment, in order to discover, whether iron, in a saline form, is

capable of entering the lacteals.

An ounce and a half of salt of steel dissolved in a sufficient quantity

of water, filtrated and mixed with about a pound of bread and milk,

were forced down the throat of a dog, that had been kept fasting for

36 hours. An hour after he had swallowed this mixture, having secured

him in a supine posture, as is usual in such experiments, we opened the

abdomen, and observed the lacteal vessels, like white threads, running

along the mesentery in a very beautiful manner. Upon slitting open part

of the small guts, we there found a good deal of the mixture, which

appeared frothy, but without any black colour, or the least sign of the

salt being precipitated; and struck a deep inky colour with infusion

of galls. Tho’ the white colour of the lacteals convinced us, that

they were full of chyle, yet, as it would have been impossible to have

collected a sufficient quantity of it from them, we found it necessary

to open the thorax, and tie the thoracic duct a little above the

receptacle, which, from the ligature, soon became turgid, the animal

being alive and warm, and the chyle still continuing its course towards

the thoracic duct. Having cut open the receptacle, we easily collected

a sufficient quantity of chyle, and immediately mixed therewith, drop

by drop, infusion of galls; a very simple and easy method, by which an

incredibly small quantity of salt of steel may be discovered in most

liquors: but not the smallest change of colour was observed, tho’ they

were rubbed together for some time, and allowed to stand several hours.

Now had there been a single atom (so to speak) of the salt in so small

a portion of chyle, as that used in this experiment, which was, as near

as I could guess, some what less than half an ounce, it is not to be

imagined, that it could have failed to discover itself by this method

of trial; for upon adding one fourth of a grain of the salt, this

mixture instantly became of a bright purple: and I have found, by other

experiments, that the smallest quantity of salt of steel shews itself

as readily in the chyle by galls, as in any other liquor of the same

consistence.

This experiment (which was as fair as could have been desired),

together with another observation I have made, _viz._ that neither the

blood nor urine of patients, during the use of salt of steel, in the

least change colour with galls, renders it more than probable, that

this salt _does not enter the blood_.

As the salt was found to have undergone no change in the small guts,

it appears, that it is not prevented from entering the lacteals by its

being decomposed or precipitated, as has been imagined; but, on the

contrary, that what renders it incapable of being received by these

vessels, is its _astringency_: for the lacteals seem to be endowed with

that admirable faculty of admitting such particles of pure chyle as

they happen to be in contact with, and of accommodating their diameters

to them, at the same time that by their natural irritability, and

power of constriction they obstinately exclude such as are astringent;

which, were they to enter the lacteals, would either produce dangerous

obstructions in these vessels, or, if they got into the blood, would

occasion polypous concretions in the larger vessels, or coagulations

incapable of being transmitted thro’ the minute vessels of the lungs;

the effects of which would be either sudden death, or at least

inflammations and suppurations from obstructions in the pulmonary

vessels; inconveniences, which nature, by precluding astringents from

entering the lacteals, has carefully and wisely avoided.

Salt of steel, taken internally, must retain its astringency until it

be precipitated; which can scarce ever fail to happen in the great

guts, from the putrid _fæces_ they contain, which are always observed

to be tinged of a black colour from the metallic basis of the salt,

part of which, as it has little or no astringency, may, no doubt,

enter the blood, as Signor Menghini observed of the _crocus_, which

is the same substance; and we know, from the experiments of Lister

and Musgrave[35], that particles much grosser than those of the white

chyle, provided they be not astringent, or very acrid, are conveyed by

the lacteals. But the metallic basis being separated from its acid, and

thus reduced to a mere calx or earth, can scarce be supposed to have

any medicinal quality whatsoever, or at least to have any share in the

virtues justly attributed to salt of steel.

As this salt is not only astringent, and consequently a strengthener,

but at the same time acts with a gentle _stimulus_, all its virtues

(which are known to be very great in diseases, where the fluids are

either viscid, cold, and phlegmatic, or dissolved and watery, from a

laxity of the solids) may be accounted for from its immediate effects

on the stomach and _primæ viæ_, and on the system of the solids in

general by consent; which it would be needless to illustrate by similar

examples, because well known to every one the least versed in medical

studies. I shall therefore only beg leave, from the obvious qualities

of this medicine, and from what has been observed above, to deduce the

following corollaries.

1. That salt of steel has no deobstruent or aperient virtue by any

immediate action, that it can possibly have on the blood, or other

animal fluids, as some have imagined; but that, on the contrary, it

owes this quality to its _not entering the blood_, which it would

otherwise coagulate, and to _its action on the solids alone_.

2. That in diseases proceeding from a laxity of the solids, great care

ought to be taken to restore and invigorate the _primæ viæ_; since a

medicine (and this we may presume not the only one) whose immediate

action is confined to those parts, is yet found by experience to

produce so salutary effects in such diseases.

3. That as this salt does not enter the blood, and consequently cannot

be in danger of too much stimulating or constricting the vessels, on

which it only acts by consent, it may, in small doses, be successfully

used in many cases, where it has been imagined to be hurtful,

particularly in consumptions of the lungs, so frequent and fatal in

this island; which are commonly attended with too great a laxity of

the _primæ viæ_, and of the solids in general, tho’ they seem more

immediately to proceed from a laxity and weakness of the pulmonary

vessels; in which circumstances it must be of the utmost consequence

to restore the tone of those principal organs of chylification, the

_primæ viæ_; as good chyle not only corrects the acrimony of the blood,

which in the advanced stages of consumptions so much prevails, but

likewise saves a great deal of labour, which the lungs (already too

much oppressed) must otherwise undergo from a crude and ill-concocted

chyle. Agreeably to this we find, in the _Essays Physical and Literary_

of Edinburgh[36], two well-vouched histories of patients far gone in

consumptions, with the usual symptoms of pain in the breast, cough,

gross spitting of fetid matter, difficulty of breathing, hectic fits,

and morning sweats, perfectly cured in a few weeks, by the use of the

Hartfell-Spaw near Moffat; which, contrary to what is observed in most

natural chalybeat waters, contains a fixed vitriol of iron.

These, Sir, are the few observations I had to make at present on this

subject. I have taken the liberty to address them to you, in order, if

you shall think proper, to be communicated to your illustrious Society;

which, I hope, will continue to latest posterity those interesting

researches for the advancement of every branch of natural knowlege, by

which it has already acquired so much and so deserved honour; and am,

with the greatest respect,

SIR,

Your most obedient humble Servant,

Edward Wright.

Strand, Feb. 28. 1758.

LXXX. _A Dissertation on the Antiquity of Glass in Windows. In a Letter

to the Rev._ Tho. Birch, _D. D. Secret. R. S. By the Rev._ John Nixon,

_M. A. F.R.S._

[Read Mar. 2, 1758.]

London, March 2. 1758.

Dear Sir,

I Had the honour last winter to lay before the Royal Society a few

observations upon some of the curiosities found at Herculaneum,

_&c._[37]. Among other articles, I just mentioned a piece of a plate

of white glass; and now beg leave to inquire into the uses, to which

such plates might be applied in the early age, to which this fragment

undoubtedly belongs.

And here a person, who forms his ideas of ancient customs by what

he sees practised in later times, may be ready to offer several

conjectures; in some of which he will, probably, be mistaken; as in

others he may be justified by the genuine evidences of antiquity.

And, first, It is obvious to imagine, that such plates might serve

for _specula_, or looking-glasses. And, indeed, that _specula_ were

anciently made, not only of metals, and some stones, as the[38]

phengites, _&c._ but also of glass, may, I think, be collected from

Pliny, who, having mentioned the city of Sidon as formerly famous for

glass-houses, adds immediately afterwards, _Siquidem etiam specula

excogitaverat_[39]. But then it is to be observed, that before the

application of quicksilver in the constructing of these glasses (which,

I presume, is of no great antiquity), the reflection of images by such

_specula_ must have been effected by their being besmeared _behind_,

or tinged _thro’_ with some dark colour, especially black, which would

obstruct the refraction of the rays of light[40]. Upon these hypotheses

(supposing the tincture to be given after fusion) the _lamina_ before

us may be allowed to be capable of answering the purpose here assigned.

It may further be suggested, that plates of this kind might be intended

to be wrought into lens’s, or convex glasses, either for burning, or

magnifying objects placed in their focus. But this designation cannot

be supported by proper vouchers from antiquity. On the contrary, we

are informed, that the ancients used either _specula_[41] of metal, or

balls[42] of glass for the former of these purposes; as it is well

known, that glass was not applied to the latter, in optical uses, till

the beginning of the XIIIth century[43].

However, we may with greater probability propose another use, for

which the ancients might employ such plates of glass, as are now under

consideration, _viz._ the adorning the walls of their apartments by

way of wainscot. This I take to be the meaning of the _vitreæ cameræ_

mentioned by Pliny[44]; who intimates, that this fashion took its rise

from glass being used by M. Scaurus[45] for embellishing the scene

of that magnificent theatre, which he erected for exhibiting shows

to the Roman people in his ædileship[46]. And we may collect from

the same author[47] (what is further confirmed by his contemporary

[48]Seneca), that this kind of ornament had been admitted, in his

time, into chambers in houses, baths, _&c._ Whether the plates used for

this purpose were stained with various colours (as mentioned above),

or had tints of divers kinds applied to the back part of them, I shall

not pretend to determine: but in either way they would have a very

agreeable effect.

The last destination, which the obvious congruity of the thing itself,

countenanced by the practice of many ages past, as well as of the

present time, would induce one to ascribe to such plates of glass, is

that of windows for houses, baths, portico’s, _&c._ But I am sensible,

that whoever should be hardy enough to advance such an hypothesis,

would be censured as an innovator, in opposing the general opinion of

the connoisseurs in antiquity. These gentlemen are almost unanimous in

asserting, that whenever we meet with mention made of _specularia_ in

ancient writers (especially those _of_, or near _to_, the age, to which

we must refer this fragment), we are to understand by that term nothing

but fences made of _laminæ_, either of a certain stone called from its

transparent quality _lapis specularis_[49], brought first from Hispania

Citerior, and afterwards found in Cyprus, Cappadocia, Sicily, and

Africa; or of another stone of the same nature, _viz._ the phengites.

These, tho’ expressly distinguished from each other by Pliny[50],

are yet reckoned by some moderns[51] as one and the same thing; and

thought to have been nothing but a kind of white transparent talc, of

which (according to Mons.[52] Valois) there is found a great quantity

in Moscovy at this day.

Now that this _lapis specularis_, or phengites, was really used for

windows by the ancient Romans in their houses, _&c._ cannot be denied;

since (according to the opinion of the learned[53] in antiquity) this

usage is mentioned by Seneca[54] among other improvements in luxury

introduced in his time. But whether it was so used exclusive of other

materials (particularly glass), may, I think, admit a doubt. Salmasius

is of opinion[55], that nothing can be determined upon this point from

the word _specular_ itself, which seems to be a generical term, equally

applicable to windows of all kinds, whether consisting of the _lapis

specularis_, or any other transparent substance.

And as (according to this learned writer) there is nothing in the term

_specular_ itself, which hinders it from being extended to windows made

of other materials besides those above-mentioned; so others imagine,

that there are some intimations in ancient authors, which require, that

it should actually be so extended. Thus Mr. Castells, the ingenious

illustrator of the villa’s of the ancients, thinks[56], that “if this

had not been the case, Palladius would not have given directions to his

husbandman to make _specularia_ in the _olearium_[57], or store-room,

where the olives were preserved. For it appears (says this author) from

Pliny’s describing a temple[58] built of the _lapis specularis_, or

phengites, as the greatest rarity in his time, and the mention Plutarch

makes of a room in Domitian’s palace lined with it, that it was not

common enough for husbandmen to purchase;” _viz._ in such quantities,

as were required for the purposes mentioned above.

I shall not take upon me to decide upon the weight of this argument of

Mr. Castells; but only observe, that if any one should be induced by

it to think, that the use of glass for windows may be of much greater

antiquity than is commonly allowed, or even as old as the fragment,

which occasions these remarks, he may find other probable reasons to

corroborate his opinion. As, first, that there seems to have been a

natural and obvious transition from the practice of using glass plates

for the ornamenting the walls of apartments to that of introducing

light into those apartments, (as we find the _lapis specularis_

was in fact employed at the same time for both those purposes) and

consequently it seems reasonable to suppose, that the latter of these

applications could not be long in point of time after the former.

But it appears from the authorities produced above, that the former

of these usages did actually subsist in the age[59] of Pliny; and

therefore before the destruction of Herculaneum, where he lost his

life[60]. From whence we may draw no improbable conclusion, that the

latter destination of plates of glass, (_viz._ for window-fences) did

likewise precede the same event.

Give me leave to add further, that this presumptive argument in

favour of the antiquity of windows made of plates of glass receives

an additional force from the close relation, which must be allowed to

subsist between them, and those composed of the _lapis specularis_. The

former must be looked upon as an improvement upon the other, as they

answered all the purposes of convenience, and at the same time were

more beautiful; and being the manufacture[61] of Italy, might probably

be purchased at a less expence. Upon all which accounts it seems

reasonable to conclude, that one of these inventions would naturally be

introductory to the other: and consequently, that as window-lights of

the _lapis specularis_ began to be used within the memory of Seneca,

who died[62] under Nero, about _anno Christi_ 68. (_Helvic._), the

original of those of glass may have fair pretensions to a place within

the period assigned in the foregoing paragraph, _viz._ some years

before the destruction[63] of Herculaneum, in whose ruins the plate

before us was buried.

To conclude: I need not observe to you, that all the evidence here

produced to prove the usage of glass-windows to have been coæval

with the fragment we are now considering, is of the conjectural kind

only: for, I must confess, I have not been able to trace it up by any

positive authority higher than about 200 years short of the epocha last

mentioned, _viz._ to the latter end of the third century[64], when

it is expresly mentioned by Lactantius in these words:--_Manifestius

est, mentem esse, quæ per oculos ea, quæ sunt opposita, transpiciat,

quasi per fenestras lucente vitro aut speculari lapide obductas._--De

opificio Dei, cap. v.

Philosophical transactions, Vol. L. Part II. For the year 1758. Giving some account of the present undertakings, studies, and labours, of the ingenious, in many considerable parts of the world. · 第 34 / 119 题