PAINTING.
The successful application of paint, whether for artistic or
preservative purposes, necessitates careful attention to a number of
considerations, some of a mechanical and others of a chemical character.
_The Surface._--Of whatever the surface may be to which the paint is
to be applied, great care must be taken that it is perfectly dry. Wood
especially, even when apparently dry, may on a damp day contain as much
as 20 per cent. of moisture. A film of paint applied to the surface
of wood in this condition prevents the moisture from escaping, and it
remains enclosed until a warm sun or artificial heat converts it into
vapour, which raises the paint and causes blisters. Moisture enclosed
between two coats of paint has the same effect. Paint rarely blisters
when applied to wood from which old paint has been burnt off; this is
probably due to the drying of the wood during the operation of burning.
When the surface to be painted is already covered with old paint, this
should be either removed or rubbed down smooth before applying the
new. When the thickness of the old coat is not great, rubbing down,
accompanied by a careful scraping of blisters and defective parts,
will suffice. When the thickness of the old paint necessitates its
removal, it may either be burned off, or softened by a solution of
caustic alkali, and afterwards scraped. The burning process is the
most effective, and leaves the wood in a fit condition to receive the
fresh coat of paint; but it is not applicable in the case of fine
mouldings. When caustic potash or soda is used, the paint is left in
contact with, it for some time, when the linoleic acid of the oxidised
linseed-oil becomes saponified, and can easily be scraped or scrubbed
off the surface of the wood.
Whenever an alkali is employed, it is of the greatest importance that
the wood should afterwards be thoroughly washed several times with
clean water, in order to remove every trace of the solvents. Any soda
or potash remaining in the pores of the wood would not only retain
moisture and cause blistering, but would also have an injurious action
upon the vehicle of the paint subsequently applied, and in many cases
upon the pigment itself. The remarks already made as to the necessity
of an absolutely dry surface should be borne in mind in this instance.
When the surface of the paint is to be protected by a coat of varnish,
the latter should not be applied until the whole of the oil contained
in the paint has solidified. The wrinkling of varnish upon paint is
frequently erroneously attributed to the bad quality of the varnish,
when the real cause is the incomplete oxidation of the paint itself.
_Priming._--The first coat of paint applied to any surface is termed
the “priming-coat.” It usually consists of red lead and boiled and raw
linseed-oil. Experience has shown that such a priming not only dries
quickly itself, but also accelerates the drying of the next coat. The
latter action must be attributed to the oxygen contained in the red
lead, only a small portion of which is absorbed by the oil with which
it is mixed.
Kali, of Heidelberg, prepares a substitute for boiled oil by mixing 10
parts whipped blood, just as it is furnished from the slaughter-houses,
with 1 part of air-slaked lime sifted into it through a fine sieve.
The two are well mixed and left standing for 24 hours. The dirty
portion that collects on top is taken off, and the solid portion is
broken loose from the lime at the bottom; the latter is stirred up with
water, left to settle, and the water is poured off after the lime has
settled. The clear liquid is well mixed up with the solid substance
before mentioned. This mass is left standing for 10 or 12 days, after
which a solution of potash permanganate is added, which decolorises it
and prevents putrefaction. Finally the mixture is stirred up, diluted
with more water to give it the consistence of very thin size, filtered,
a few drops of oil of lavender are added, and the preparation is
preserved in closed vessels. It is said to keep a long time without
change. A single coat of this liquid will suffice to prepare wood or
paper, as well as lime or hard plaster walls, for painting with oil
colours. This substance is cheaper than linseed oil, and closes the
pores of the surface so perfectly that it takes much less paint to
cover it than when primed with oil.
_Drying._--The drying of paint is to a great extent dependent upon the
temperature. Below the freezing point of water, paint will remain wet
for weeks, even when mixed with a considerable proportion of dryers;
while, if exposed to a heat of 120° F. the same paint will become solid
in a few hours. The drying of paint being a process of oxidation, and
not evaporation, it is essential that a good supply of fresh air should
be provided. When a film of fresh paint is placed with air in a closed
vessel, it does not absorb the whole of the oxygen present; but after a
time the drying process is arrested, and the remaining oxygen appears
to have become inert.
Considerable quantities of volatile vapours are given off during the
drying of paint; these are due to the decomposition of the oil. When
the paint has been thinned down by turpentine, the whole of this
liquid evaporates on exposure to the air. There must, therefore, be
a plentiful access of air, to remove the vapours formed, and afford
a fresh supply of active oxygen. The presence of moisture in the air
is rather beneficial than injurious at this stage. Especially in the
case of paints mixed with varnish, moist air appears to counteract the
tendency to crack or shrink. Under the erroneous impression that the
drying of paint is a species of evaporation, open fires are sometimes
kept up in freshly-painted rooms. It is only when the temperature is
very low that any benefit can result from this practice; as a rule, it
rather retards than hastens the solidification of the oil, which cannot
take place rapidly in an atmosphere laden with carbonic acid.
The first coat of paint should be thoroughly dry before the second is
applied. Acrylic acid is formed during the oxidation of linseed-oil,
and unless this be allowed to evaporate, it may subsequently liberate
carbonic acid from the white lead present in most paints, and give rise
to blisters. Sometimes a second priming-coat is given; but usually
the second coat applied contains the pigment. This, as soon as dry,
is again covered by another coat, and subsequently by two or more
finishing coats, according to the nature of the work.
_Filling._--Before the first coat is applied to wood, all holes should
be filled up. The filling usually employed is ordinary putty; this,
however, sometimes consists of whiting ground up with oil foots of a
non-drying character, and when the films of paint are dry, the oil from
the putty exudes to the surface, causing a stain. The best filling for
ordinary purposes is whiting ground to a paste with boiled linseed-oil.
For finer work, and for filling cracks, red lead mixed with the same
vehicle may be employed. For porous hard woods, use boiled oil and
corn starch stirred into a very thick paste; add a little japan, and
reduce with turpentine. Add no colour for light ash; for dark ash and
chestnut, use a little raw sienna; for walnut, burnt umber and a slight
amount of Venetian red; for bay wood, burnt sienna. In no case use
more colour than is required to overcome the white appearance of the
starch, unless you wish to stain the wood. This filler is worked with
brush and rags in the usual manner. Let it dry 48 hours, or until it
is in condition to rub down with No. 0 sand-paper without much gumming
up; and if an extra fine finish is desired, fill again with the same
materials, using less oil, but more japan and turpentine. The second
coat will not shrink, being supported by the first. When the second
coat is hard, the wood is ready for finishing up by following the usual
methods. This formula is not intended for rosewood.
_Coats._--There is no advantage in laying on the paint too thickly.
A thick film takes longer to dry thoroughly than two thin films of
the same aggregate thickness. Paint is thinned down or diluted with
linseed-oil or turpentine. The latter liquid, when used in excess,
causes the paint to dry with a dull surface, and has an injurious
effect upon its stability. Sometimes the last coat of paint is mixed
with varnish, in order to give it greater brilliancy. In this case,
special care must be taken that the previous coats have thoroughly
solidified, or cracks in the final coat may subsequently appear. The
same remark applies when the surface of the paint is varnished. The
turpentine with which the varnish is mixed has a powerful action
upon the oil contained in the paint, if the latter is not thoroughly
oxidised. The exterior of the paint is thus softened, and the varnish
is enabled to shrink and crack, especially in warm weather.
_Brushes._--The bristles are frequently fastened by glue or size, which
is not perceptibly acted upon by oil, and if brought into contact with
this liquid alone, there would be no complaints of loose hairs coming
out and spoiling the work. It is a common practice to leave the brushes
in a paint-pot, in which the paint is covered with water to keep it
from drying. The brushes are certainly kept soft and pliant in this
way; but at the same time the glue is softened, and the bristles come
out as soon as the brush is used. After use, brushes should be cleaned,
and placed in linseed-oil until again required, when they will be found
in good condition. Treated in this way, they will wear so much better
that the little additional trouble entailed is amply repaid. When
brushes will not again be required for some time, the oil remaining in
them should be washed out by means of turpentine, after which they may
be dried without deterioration. On no account should oil be allowed
to dry in a brush, as it is most difficult to remove after oxidation
has taken place. The best means are steeping in benzoline for a few
days, or in turpentine, with occasional washing in soda-water and with
soft-soap, avoiding too violent rubbing.
_Water-colours._--The manufacture of water-colour paints is more simple
than that of oil paints, the pigments being first ground extremely
fine and then mixed with a solution of gum or glue. The paste produced
in this manner is allowed to dry, after having been stamped into the
form of cakes. As soon as the hardened mass is rubbed down with water,
the gum softens and dissolves, and if the proportion of water be not
too great, the pigment will remain suspended in the solution of gum,
and can be applied in the same manner as oil-paint. To facilitate the
mixing with water, glycerine is sometimes added to the cake of paint,
which then remains moist and soft.
_Removing Odour._--(1) Place a vessel of lighted charcoal in the room,
and throw on it 2 or 3 handfuls of juniper berries; shut the windows,
the chimney, and the door close; 24 hours afterwards the room may be
opened, when it will be found that the sickly, unwholesome smell will
be entirely gone. (2) Plunge a handful of hay into a pail of water, and
let it stand in the room newly painted.
_Discoloration._--Light-coloured paints, especially those having white
lead as a basis, rapidly discolour under different circumstances. Thus
white paint discolours when excluded from the light; stone colours lose
their tone when exposed to sulphuretted hydrogen, even when that is
only present in very small quantity in the air; greens fade or darken,
and vermilion loses its brilliancy rapidly in a smoky atmosphere like
that of London.
Ludersdorf thinks that the destructive change is principally due to
a property in linseed-oil which cannot be destroyed. The utility of
drying oils for mixing pigments depends entirely on the fact that
they are converted by the absorption of oxygen into a kind of resin,
which retains the colouring pigment in its semblance; but during
this oxidation of the oil--the drying of the paint--a process is set
up which, especially in the absence of light and air, soon gives
the whitest paint a yellow tinge. Ludersdorf therefore proposes
to employ an already formed but colourless resin as the binding
material of the paint, and he selects two resins as being specially
suitable--one, sandarach, soluble in alcohol; the other, dammar,
soluble in turpentine. The sandarach must be carefully picked over, and
7 oz. is added to 2 oz. Venice turpentine and 24 oz. alcohol of sp.
gr. 0·833. The mixture is put in a suitable vessel over a slow fire
or spirit-lamp, and heated, stirring diligently, until it is almost
boiling. If the mixture be kept at this temperature, with frequent
stirring for an hour, the resin will be dissolved, and the varnish is
ready for use as soon as cool. The Venice turpentine is necessary to
prevent too rapid drying, and more dilute alcohol cannot be employed,
because sandarach does not dissolve easily in weaker alcohol, and,
furthermore, the alcohol, by evaporation, would soon become so weak
that the resin would be precipitated as a powder.
When this is to be mixed with white lead, the latter must first be
finely ground in water, and dried again. It is then rubbed with a
little turpentine on a slab, no more turpentine being taken than is
absolutely necessary to enable it to be worked with the muller; 1 lb.
of the white lead is then mixed with exactly ½ lb. of varnish, and
stirred up for use. It must be applied rapidly, because it dries so
quickly. If when dry the colour is wanting in lustre, it indicates the
use of too much varnish. In such cases, the article painted should be
rubbed, when perfectly dry, with a woollen cloth to give it a gloss.
The dammar varnish is made by heating 8 oz. dammar in 16 oz. turpentine
oil at 165° to 190° F., stirring diligently, and keeping it at this
temperature until all is dissolved, which requires about an hour. The
varnish is then decanted from any impurities, and preserved for use.
The second coat of the pure varnish, to which half its weight of oil of
turpentine has been added, may be applied. It is still better to apply
a coat of sandarach varnish made with alcohol, because dammar varnish
alone does not possess the hardness of sandarach, and when the article
covered with it is handled much, does not last so long.
_Composition._--The composition of paints should be governed--
(1) By the nature of the material to be painted: thus the paints
respectively best adapted for wood and iron differ considerably.
(2) By the kind of surface to be covered: a porous surface requires
more oil than one that is impervious.
(3) By the nature and appearance of the work to be done: delicate tints
require colourless oil, a flatted surface must be painted without oil
(which gives gloss to a shining surface), paint for surfaces intended
to be varnished must contain a minimum of oil.
(4) By the climate and the degree of exposure to which the work will be
subjected: for outside work, boiled oil is used, because it weathers
better than raw oil; turps is avoided as much as possible, because it
evaporates and does not last; if, however, the work is to be exposed to
the sun, turps is necessary, to prevent the paint from blistering.
(5) The skill of the painter affects the composition: a good workman
can lay on even coats with a smaller quantity of oil and turps than
one who is unskilful; extra turps, especially, are often added to save
labour.
(6) The quality of the materials makes an important difference in the
proportions used: thus more oil and turps will combine with pure than
with impure white lead; thick oil must be used in greater quantity than
thin when paint is purchased ready ground in oil, a soft paste will
require less turps and oil for thinning than a thick.
(7) The different coats of paint vary in their composition: the first
coat laid on to new work requires a good deal of oil to soak into the
material; on old work, the first coat requires turpentine to make it
adhere; the intermediate coats contain a proportion of turpentine to
make them work smoothly; and to the final coats the colouring materials
are added, the remainder of the ingredients being varied according as
the surface is to be glossy or flat.
The exact proportions of ingredients best to be used in mixing paints
vary according to their quality, the nature of the work required,
the climate, and other considerations. The composition of paint for
different coats also varies considerably. The proportions given in the
following table must only be taken as an approximate guide when the
materials are of good quality:--
TABLE showing the COMPOSITION of the different
COATS of WHITE PAINT, and the QUANTITIES
required to cover 100 yd. of NEWLY-WORKED PINE.
--------------+-----+-------+------+------+-----+------+---------
|Red | White | Raw |Boiled|Turp.|Dryers|REMARKS
|lead | lead. | Lins.|Lins. | | |(see
| | | oil | oil | | |footnotes)
--------------+-----+-------+------+------+-----+------+---------
_Inside work, | | | | | | |
4 coats not | | | | | | | [A]
flatted._ | lb. | lb. | pt. | pt. | pt. | lb. |
| | | | | | |
Priming | ½ | 16 | 6 | -- | -- | ¼ |
2nd coat | [B] | 15 | 3½ | -- | 1½ | ¼ |
3rd coat | -- | 13 | 2½ | -- | 1½ | ¼ |
4th coat | -- | 13 | 2½ | -- | 1½ | ¼ |
| | | | | | |
_Inside work | | | | | | |
4 coats & | | | | | | |
flatting._ | | | | | | |
Priming |1½ | 16 | 6 | -- | ½ | 1-8 |
2nd coat | -- | 12 | 4 | -- | 1½ | 1-10|
3rd coat | -- | 12 | 4 | -- | 0 | 1-10|
4th coat | -- | 12 | 4 | -- | 0 | 1-10|
Flatting | -- | 9 | 0 | -- | 3½ | 1-10|
| | | | | | |
_Outside work | | | | | | | [C]
4 coats not | | | | | | |
flatted._ | | | | | | |
Priming | 2 | 18½ | 2 | 2 | -- | 1-8 |
2nd coat | -- | 15 | 2 | 2 | ½ | 1-10|
3rd coat | -- | 15 | 2 | 2 | ½ | 1-10|
4th coat | -- | 15 | 3 | 2½ | 0 | 1-10|
---------------------------------------------------------------
[A] Sometimes more red lead is used and less dryer.
[B] Sometimes just enough red lead is used to give a flesh-coloured
tint.
[C] When the finished colour is not to be pure white, it is better to
have nearly all the oil boiled oil. All boiled oil does not work well.
For pure white a larger proportion of raw oil is necessary, because
boiled oil is too dark.
_Area Covered._--For every 100 sq. yd., besides the material enumerated
in the foregoing, 2½ lb. white lead and 5 lb. putty will be required
for stopping. The area which a given quantity of paint will cover
depends upon the nature of the surface to which it is applied, the
proportion of the ingredients, and the state of the weather. When the
work is required to dry quickly, more turpentine is added to all the
coats. In repainting old work, two coats are generally required, the
old paint being considered as priming. Sometimes another coat may
be deemed necessary. For outside old work exposed to the sun, both
coats should contain 1 pint turpentine and 4 pints boiled oil, the
remaining ingredients being as stated in the foregoing table. The
extra turpentine is used to prevent blistering. In cold weather, more
turpentine should be used to make the paint flow freely.
According to another authority, it is found that in painting wood,
one coat takes 20 lb. lead and 4 gal. oil per 100 sq. yd.; the second
coat, 40 lb. lead and 4 gal. oil; and the third the same as the second;
say 100 lb. lead and 16 gal. oil per sq. yd. for the three coats. The
number of square yards covered by one gallon of priming colour is found
to be 50; of white zinc, 50; of white lead paint, 44; of lead colour,
50; of black paint, 50; of stone colour, 44; of yellow paint, 44; of
blue colour, 45; of green paint, 45.
_Measuring._--Surface painting is measured by the superficial yard,
girting every part of the work covered, always making allowance for
the deep cuttings in mouldings, carved work, railings, or other work
that is difficult to get at. Where work is very high, and scaffolding
or ladders have to be employed, allowances must be made. The
following rules are generally adopted in America in the measurement
of work:--Surfaces under 6 in. in width or girt are called 6 in.;
from 6 to 12 in., 12 in.; over 12 in., measured superficial. Openings
are deducted, but all jambs, reveals, or casings are measured girt.
Sashes are measured solid if more than two lights. Doors, shutters and
panelling are measured by the girt, running the tape in all quirks,
angles or corners. Sash doors measure solid. Glazing, in both windows
and doors, is always extra. The tape should be run close in over the
battens, on batten doors, and if the stuff is beaded, add 1 in. in
width for each bead. Venetian blinds are measured double. Dentels,
brackets, medallions, ornamented iron work, balusters, lattice work,
palings, or turned work, should all be measured double. Changing
colours on base boards, panels, cornices, or other work, one-fourth
extra measurement should be allowed for each tint. Add 5 per cent. to
regular price for knotting, puttying, cleaning, and sand-papering. For
work done above the ground floor, charge as follows:--Add 5 per cent.
for each story of 12 ft. or less, if interior work; if exterior work,
add 1 per cent. for each foot of height above the first 12 ft.
CARRIAGE AND CAR PAINTING.--The following is the substance of
an address delivered by McKeon, secretary and treasurer of the Master
Car-Painters’ Association of the United States:--A first-class railway
coach costs, when complete, about 1200_l._ To protect this work, the
painter expends 60_l._ to 120_l._ The latter figure will make a first
class job. The car has been completed in the wood-shop, and is turned
over to the painter, who is responsible for the finish. He is expected
to smooth over all rough places or defects in the wood, which requires
both patience and skill to make the work look well. Twelve weeks should
be the time allowed to paint a car, and it cannot be done in any less
time, to make a good job that will be a credit to the painter and all
other parties interested in the construction and finish of the car. Too
much painting is done in a hurry: proper time is not given the work to
dry or become thoroughly hardened before it is run out of the shop, and
consequently it does not always give the satisfaction it should; nor
can it be expected that hurried work will be so lasting or durable as
that which has the necessary time given to finish it.
_Priming Paint._--The priming coat of paint on a car is of as much
importance as any succeeding one, and perhaps more. Good work is ruined
in the priming by little or no attention being given by the painter to
the mixing and application of the first coat. The foundation is the
support, and on that rests success or failure. The priming should be
made of the proper material, mixed with care from good lead and good
oil, and not picked up from old paints which have been standing mixed,
and must necessarily be fat and gummy, for such are unfit for use on
a good job, and will have a decided tendency to spoil the whole work.
Special care should be exercised, both in mixing and applying the
priming, and it should be put on very light, so that it may penetrate
well into the wood. Too much oil is worse than not enough. Good ground
lead is by far the best material for the undercoats on a car. Two coats
should be given to the car before it is puttied, as it is best to fill
well with paint the nail-holes and plugs, as well as defects in the
wood, so that moisture may not secure a lodgment, which otherwise will
cause the putty to swell, although sometimes unseasoned lumber will
swell the putty; and as it shrinks, the nail remains stationary, and of
course the putty must give way.
_Best Putty._--In mixing putty, which may be a small matter with some,
take care to so prepare it that it will dry perfectly hard in 18 hours.
Use ground lead and japan, stiffening up with dry lead, and whatever
colouring you may require in it to match your priming coats.
The next coats, after the work is well puttied, should be made to dry
flat and hard. Two coats should be applied, and, for all ordinary
jobs or cheap work, sand-papering is all that is necessary for each
coat; but when a good surface is required, I would recommend one coat
to be put on heavy enough to fill the grain; and before being set,
scrape with a steel scraper. The plain surface is all that requires
coating and scraping with the heavy mixture. For this coat, which is
called filling, use one-half ground lead and any good mineral which
experience has shown can be relied on. This scraping of the panel work
will fill the wood equal to two coats of rough stuff, and saves a great
amount of labour over the old process, when so much rubbing with lump
pumice was done. Sand-paper when the filling is thoroughly hard, and
apply another coat of paint of ordinary thickness, when, after another
sand-papering, you have a good surface for your colour.
Rough-coating on cars has gone almost out of use, and few shops are now
using it to any extent. My experience is that paint has less tendency
to crack where rough stuff is left off. I do not claim that the filling
was the principal cause of the cracking, if it was properly mixed; but
I believe the water used in rubbing down a car with the lump pumice
injures the paint, as it will penetrate in some places, particularly
around the moulding plugs.
_Finishing Colour._--The car being ready for the finishing colour, this
should be mixed with the same proportion of dryer as the previous coat,
or just sufficient to have it dry in about the same time. A great error
with many car painters is using a large portion of oil in the under
coats, and then but little, if any, in the finishing coats; this has a
decided tendency to crack, the under coats being more elastic. Always
aim to have colour dry in about the same time, after you have done
your priming; by this plan you secure what all painters should labour
to accomplish--namely, little liability to crack. Work will of course
crack sometimes after being out a few months, or when it has repeated
coatings of varnish; and using a quick rubbing varnish on work will
cause it to give way in fine checks quicker than anything else. Many of
the varnishes used are the cause of the paint cracking, and no painter
has been wholly exempt from this trouble.
_Cause of Cracking._--The most common cause of cracking is poor japan,
which is the worst enemy that the car-painter has to contend with. The
greater part of the japan is too elastic, and will dry with a tack,
and the japan gold size has generally the same fault, although the
English gold size is generally of good quality; but its high price
is an objection to its use. A little more care in the manufacture
of japans would give a better dryer, and few would object to the
additional cost. Japan frequently curdles in the paint; it will not mix
with it, but gathers in small gummy particles on the top. Work painted
with such material cannot do otherwise than crack and scale, and the
remedy lies only in getting a good pure article of turpentine japan.
In regard to using ground lead, car-painters differ, as some prefer
to grind their own in the shop. I use the manufactured lead, and my
reasons for doing so are that it is generally finer than any shop can
grind it with present facilities, and it has age after grinding, which
improves its quality. You can also get a purer lead and one with more
body than you can by grinding in the shop, which is a fact that I think
most painters must admit. I have tested it very fully, and am convinced
on this point.
_Mixing the Paints._--Permit me to make a few suggestions here in
regard to the mixing of paint, which may not fully agree with others’
views. There is just as much paint that cracks by putting it on too
flat as by using too much oil. Some painters mix their finishing colour
so that it is impossible to get over a panel of ordinary size before
it is set under the brush, and consequently the colour will rough up.
Colour should be mixed up so that it will not flat down for some time
after leaving it, and then you have got some substance that will not
absorb the varnish as fast as it is applied to the surface. This quick
drying of colour is not always caused by want of oil in it, but because
there is too much japan, and a less quantity of the latter will do
better work, and make a smoother finish. Give your colour 48 hours to
dry between coats; always give that time, unless it is a hurried job,
and experience has fully demonstrated that it is poor economy to hurry
work out of the shop before it is properly finished.
_Oils, Dryers, and Colours._--In car-painting, both raw and boiled oils
are used, and good work may be done with either, but I recommend oil
that is but slightly boiled, in preference to either the raw or the
boiled. After it is boiled, if it is done in the shop, let it stand
24 hours to settle, then strain off carefully; this takes out all the
impurities and fatty matter from the oil, and it will dry much better,
nor will it have that tack after drying that you find with common
boiled oil. Use the proper quantity of dryer in mixing your paint,
and a good reliable job will be the result. In car-painting, never
use prepared colours which are ground in oil, as nine-tenths of such
colours are ground in very inferior oil, and they may have been put up
for a great length of time, in which case they become fatty, and will
invariably crack. These canned colours do not improve with age, as lead
and varnish do.
Finishing colours should all be ground in the shop, unless special
arrangements can be made with manufacturers to prepare them; and the
colour should be fresh, not over 6 or 8 days old after being mixed,
and open to the air. Enough may be prepared at a time to complete the
coating on a job; but when colour stands over a week it is not fit to
use on first-class work, as it becomes lifeless, and has lost that
free working which we find in freshly-mixed colours. Such colour may,
however, be used upon a cheap class of work, or on trucks, steps, &c.,
so that nothing need be wasted in the shop.
_Varnishing._--Three coats of varnish over the colour are necessary on
a first-class coach. The first coat should be a hard drying varnish
put on the flat colour; the quick rubbing that some use I would not
recommend, but one that will dry in five days (in good drying weather)
sufficiently hard to rub, is the best for durability. After striping
and ornamenting the car, and when thoroughly washed, give a coat of
medium dry varnish. Let this stand 8 days; then rub lightly with curled
hair or fine pumice, and apply the finishing coat, which is “wearing
body;” this will dry hard in about 10 days, after which the car may
be run out of the shop. It should then be washed with cold water and
a soft brush, and is ready for the road. In varnishing, many will
apply the varnish as heavy as they can possibly make it lie, when, as
a consequence, it flows over and runs or sags down in ridges, and of
course does not harden properly; this also leaves a substance for the
weather to act on. It is better to get just enough on at a coat to make
a good even coating which will flow out smooth, and this will dry hard,
and will certainly wear better than the coat that is piled on heavily.
Varnishing, we claim, can be over-done, despite some painters’ opinions
to the contrary. We have heard of those who put 2½ gal. on the body
of a 50-foot car at one application, and we have also listened to the
declaration, made by a member of the craft, that he put 2 gal. on the
body of a locomotive tank. Such things are perhaps possible, and may
have been done; but if so, we know that the work never stood as well as
it would if done with one-half the quantity to a coat. In varnishing
a car, care should be taken to have the surface clean; water never
injures paint where it is used for washing; and a proper attention
to cleanliness in this respect, and in the care of brushes used for
varnishing, will ensure a good-looking job.
Perhaps your shop facilities for doing work are none of the best, but
do the best you can with what you have. Select if possible, a still,
dry day for varnishing, especially for the finishing coat. Keep your
shop at an even temperature; avoid cold draughts on the car from doors
and windows; wet the floor only just sufficient to lay the dust, for
if too wet, the dampness arising will have a tendency to destroy the
lustre of your varnish. Of course we cannot always do varnishing to our
perfect satisfaction, especially where there are 25 or 30 men at work
in an open shop, and 6 or 8 cars are being painted, when more or less
dirt and dust are sure to get on the work.
A suggestion might here be made to railroad managers, which is that
no paint-shop is complete where the entire process of painting and
finishing a car is to be done in one open shop. A paint-shop should
be made to shut off in sections by sliding doors, one part of the
shop being used exclusively for striping and varnishing. I know from
experience that nine-tenths of the railroad paint-shops are deficient
in this particular, and still we are expected to turn out a clean job,
no matter what difficulties we are compelled to labour under.
_Importance of Washing Cars._--In regard to the care of a car after it
has left the shop, more attention should be given to this than is done
on many roads. The car should not be allowed to run until it is past
remedy, and the dirt and smoke become imbedded in the varnish, actually
forming a part of the coating, so that when you undertake to clean the
car you must use soda or soap strong enough to cut the varnish before
you succeed in removing the dirt. Cars should be washed well with a
brush and water at the end of every trip. This only will obviate the
difficulty, and these repeated washings will harden the varnish as well
as increase its lustre. We know that, in washing a car, where soap is
required to remove the dirt and smoke, it is almost impossible to get
the smoke washed off clean; and if it is not quite impossible, the hot
sun and rain will act on the varnish and very soon destroy it.
_Re-varnishing._--Cars should be taken in and re-varnished at least
once in 12 months; and if done once in 8 months it is better for them,
and they will require only one coat; but where they run a year, they
will generally need two coats. Those varnished during the hot months
will not stand as well as if done at any other time. Painting done in
extremely cold weather, or in a cold shop, is more liable to crack than
if done in warm weather.
_How to Dry Paint._--Paint dried in the shop where there is a draught
of dry air passing through, will stand better than that dried by
artificial heat; and you will find, by giving it your attention, that
work which has failed to stand, and which cracked or scaled, was
invariably painted in the winter season, or in cool, wet weather. I
have paid some attention to this matter, and know the result.
WOODWORK PAINTING.--One of the attendant drawbacks of houses
that are newly built, or have been hastily finished for letting, is
the inferior painting of the woodwork, and its speedy destruction. The
wood is not thoroughly dry, and the consequence is the preparatory coat
does not adhere; the pores being full of dampness, it is impossible for
the oil to sink into them, especially as oil and water are unmiscible.
Another equally injurious condition is the gum-resin which exudes from
the knots of new pine and other timber. Painted over before it has
time to come to the surface, the coat is destroyed by the action of
the gum. Now, these evils have to be endured so long as the wood has
no time to get seasoned. The painter follows the carpenter without any
interval of time, and before the action of the weather can bring out
the moisture and resinous substances. A coating of shellac is usually
given to the knots, though this is often so thin as to be worthless.
Crude petroleum, as a preservative coat, is found to be an admirable
preparation for the painting. The petroleum is thin, and penetrates the
wood, filling up the pores, and giving a good ground for the coats of
paint.
According to one American authority, the preparation is of great value.
The priming coat should be thin and well rubbed in, and it is better
to use a darker colour than white lead as a base. White lead forms a
dense covering to the surface, though it has its disadvantages. When
petroleum has formed the first coat, two other coats will suffice,
one being the priming coat, and a third coat may be given after the
work has stood for a season. It is a very desirable plan to leave
the painting, or rather finishing coats, for a time, so that any
imperfections in the wood or work may be discovered; it also allows
time for any change of colour that may be made. After the priming
coat, it is usual in good work to stop all cracks, nail-holes, and
other defects with putty; but in the commoner class of paintings, the
coats are laid on quickly, the preceding coat has hardly time to dry
before the next is put on, and all the defects of wood, bad seasoning,
exudation of gum, &c., quickly begin to show themselves through and
disfigure the work.
A good paint ought to possess body, power of covering, and flow evenly
from the brush, and become hard. Though zinc white has less body than
white lead, it is more durable, and will stand sulphur acids without
blackening. Some colours stand better than others; the ochres, Indian
and Venetian reds, burnt and raw umber, are reliable, and may be
used without scruple. It is also worthy of notice that salt air acts
injuriously on white lead, and zinc white is therefore preferable in
situations exposed to the sea-air. (_English Mechanic._)
IRON PAINTING.--The decay of iron becomes very marked in
certain situations, and weakens the metal in direct proportion to the
depth to which it has penetrated; and although where the metal is in
quantity this is not very appreciable, it really becomes so when the
metal is under ¾ inch in thickness. The natural surface of cast iron is
very much harder than the interior, occasioned no doubt by its becoming
chilled, or by its containing a large quantity of silica, and this
affords an excellent protection.
But should this surface be at all broken, rust immediately attacks
the metal and soon destroys it. It is very desirable that the casting
be protected, and a priming coat of oil or paint should be applied
for this purpose; the other coats, though requisite, can be given at
leisure.
The following is a process to which all cast-iron water pipes should be
submitted. It was introduced by Dr. Smith, and is equally applicable to
any other casting that can be manipulated:--Each casting is thoroughly
dressed, and made clean and free from the earth and sand which cling
to the iron in the moulds, hard brushes being used in finishing the
process to remove the loose dust. Every casting must be likewise free
from rust when the paint is applied. If the casting cannot promptly be
dipped after being cleansed, the surface must be oiled with linseed oil
to preserve it until it is ready to be dipped. No casting is on any
account to be dipped after rust has set in. The coal-tar pitch used
as a paint in this process is made from coal-tar distilled until the
naphtha is entirely removed and the material is deodorised. In England
it is distilled until the pitch is about the consistence of wax. The
mixture of 5 or 6 per cent. of linseed oil is recommended by Dr. Smith.
Pitch which becomes hard and brittle when cold will not answer for
this use. Pitch of the proper quality having been obtained, it must be
carefully heated in a suitable vessel to a temperature of 300° F., and
must be maintained at not less than this temperature during the time
of dipping. The material will thicken, and deteriorate after a number
of pieces have been dipped; fresh pitch must, therefore, frequently be
added, and occasionally the vessel must be entirely emptied of its old
contents and refilled with fresh pitch. The refuse will be hard and
brittle like common pitch, and consequently worthless for the purpose.
Every casting must attain a temperature of 300° F., either by previous
heating or during the immersion before being removed from the vessel of
hot pitch. It may then be slowly removed, and laid upon skids to drip.
In the case of water pipes, all those of 20 inches diameter and upwards
will have to remain at least 30 minutes in the hot fluid to attain this
temperature. The coating when cold should be tough and tenacious, and
not brittle nor have the slightest tendency to scale off.
In considering the painting of wrought iron it must be noticed that
when iron is oxidised by heating in contact with the atmosphere, two
or three distinct layers of scale form on the surface, and, unlike
the skin upon cast iron, can be readily detached, as by bending or by
hammering the metal. The outer layer of this scale is more highly
oxidised than the inner, and is slightly redder in tinge from the
presence of a variable excess of ferric oxide over that contained in
the inner layer. The oxide occurring in the outer scale is fusible only
at a high temperature, is strongly magnetic, and slightly metallic in
lustre; while the inner layers are more porous, dull, and non-metallic
in lustre, less brittle, and also less powerfully magnetic. It will be
seen that the iron has a tendency to rust from the moment it leaves the
hammer or rolls, and that the scale above described must come away. One
of the plans to preserve the iron has been to coat it with paint when
still hot at the mill; and although this answers for a while, it is
a very troublesome method, which iron-masters cannot be persuaded to
adopt, and the subsequent cutting processes to which it is submitted
leave many parts of the iron bare. Besides, a good deal of the scale
remains, and until this has fallen off, or has been removed, any
painting over it will be of little value. The only effectual way of
preparing wrought iron is to effect a thorough and chemical cleansing
of the surface of the metal upon which the paint is to be applied, that
is, it must be immersed for three or four hours in water containing
from 1 to 2 per cent. of sulphuric acid. The metal is afterwards rinsed
in cold water, and, if necessary, scoured with sand, put again into the
acid bath or pickle, and then well rinsed.
The real value of any paint depends upon the quality of the linseed
oil, the quality and character of the pigment, and the care bestowed
on the grinding and mixing, and as all this is entirely a matter of
expense, cheap paints are not to be relied upon. The superiority of
most esteemed paints is due to the above causes rather than to any
unknown process or material employed in the manufacture.
The following excellent article on the preservation of iron and steel
structural work appeared in the ‘Illustrated Carpenter and Builder.’ It
conveys the most recent American opinion.
One of the most important economic questions of the present day is the
preservation of iron and steel structures. In America many millions of
dollars are annually spent in the erection and construction of these,
and the amount is increasing in rapid proportion. Bridges, buildings,
viaducts, ships, and machinery are now being made of these materials,
to almost the entire exclusion of others. From their very nature iron
and steel are peculiarly subject to decay from atmospheric and other
influences. The question of preserving them is not merely one of
finance, but, especially in the case of railroads, one affecting the
lives and property of a large portion of the community. What, then, is
the best method of preserving them?
The almost universal method is by means of paints, or the application
of substances to their surfaces which will resist or retard the
influence of air, water, and other destructive agencies. The requisites
of a good paint for this purpose are that it shall adhere firmly to
the surface, and not chip or peel off, thereby leaving portions of
the surface exposed. It must not corrode the iron, else the remedy
may only aggravate the disease. It must form a surface hard enough to
resist influences which would remove it by friction, yet elastic enough
to conform to the expansion and contraction of the metal by heat and
cold. It must be impervious to and unaffected, as far as possible, by
moisture, atmospheric and other influences to which the structure may
be exposed.
The paints that have been used for this purpose are principally asphalt
and coal-tar paints, consisting of mineral and artificial asphalt or
coal-tar, either applied alone or combined with each other, and, more
or less, with metallic bases, and iron oxide paints and lead oxide
paints, especially red lead, in all of which the pigment is held to
the surface of the iron or steel by combination with linseed oil. The
choice of paints must lie, so far as our present practical experience
goes, between these three classes, zinc oxide being found to be
entirely unsuitable on account of a propensity to peel off. What,
then, is found to be the experience in actual practice with these?
Asphalt and coal-tar paints “run” when exposed to the sun and other
sources of heat, which is a serious matter with vertical surfaces;
and after a time become extremely brittle and scale off entirely,
leaving the under surface exposed, unless the paint is constantly
renewed. In the meantime the exposed iron and steel are being corroded
by rust. Iron oxide paints, including “metallic brown,” are paints
made from iron ore, or by some chemical process with an iron base.
These are invariably iron in a greater or less degree of oxidation,
or in other words, rusted iron. Now it is well known that one of the
most active promoters of rust or decay in iron is the rust itself.
Under the combined influences of the moisture and carbonic acid of the
atmosphere, iron oxide or iron rust becomes a carrier of oxygen from
the air to the metal, rust begetting rust. It is therefore evident
that this material alone has no preserving effect on iron; in fact, it
promoted its decay.
How is it when combined with linseed oil in the form of paint? In the
economy of nature, iron oxide is a great disinfectant. When in contact
with organic matter and moisture, even at a low temperature, under
favourable conditions, it readily gives up oxygen, destroying more or
less the organic matter, and being itself reduced to a lower oxide.
When thus reduced, with equal readiness it absorbs oxygen from the
atmosphere, and again passes it on, thereby promoting and eventually
ensuring the destruction or transformation of the organic matter with
which it may be in contact, either in the soil or elsewhere. The same
process appears to take place when combined with linseed oil in the
form of paint and exposed to atmospheric influences, the oil being the
organic matter. If linseed oil in drying formed an air-and water-proof
film, it might be urged that the oxide of iron would be entirely
protected from the direct influences of oxygen of the air and moisture.
Such however is not the case.
The most eminent authorities have recently shown that the dried film
of linseed oil, unless united with a pigment that combines chemically
and forms a water-proof coating with it, actually absorbs water very
much like a sponge. Where water will go air will also go, and we thus
have in direct contact with the iron oxide of the paint, which does
not combine chemically with oil, those elements, air, moisture, and
organic matter, which cause the iron to become a carrier of oxygen and
a destroyer of what it is in contact with. It is well known that iron
paint darkens with age; this is caused largely by the iron oxide losing
oxygen, which is partly transferred to the oil, burning it up and
destroying its tenacity, as may be seen by examining iron structures
painted for some time with iron paint or metallic brown, the paint
being found extremely brittle and in feathery scales. This is not
all the damage that is done. The iron oxide in the paint becomes a
carrier of oxygen to the very metal it was designed to protect, and the
process of corrosion is commenced and carried on under the paint, which
eventually peels or scales off, the surface of the metal being found
more or less oxidised and corroded.
Asphalt and iron oxide being thus shown to be entirely incapable of
preserving the iron, it remains for us to consider the effect of red
lead. This pigment has the property of forming with linseed oil a hard
elastic coating, clinging with great tenacity to the metal. It has no
oxidising effect on iron, and does not act as a carrier of oxygen from
the atmosphere after the paint has set, neither does it render the
oil brittle nor promote rust. When red lead fails, it is principally
by gradual wear or friction from the outside. It does not scale or
blister, which both asphalt and iron oxide paints will do, thereby
requiring a thorough scraping and removal of old material before a new
coat can be applied. Any red lead pigment adhering to the metal forms
a permanent base for subsequent paintings, and is utilised in further
preserving the metal. The U.S. Government specifications for ironwork
in the new Library Building of Congress provide that “all the work
not Bower-Barffed must be given one coat of pure red lead paint--not
metallic paint of any kind, but pure red lead--before leaving the shop
and becoming rusted.”
The experiments of the U.S. Navy Department on the preservation and
fouling of plates covered with different pigments may be interesting.
A plate of iron covered with asphalt paint was immersed in sea-water
for eight months and six days at the U.S. Navy Yard, Portsmouth, N.H.
At the end of that period it was found to be covered with scum and mud,
and very badly rusted. A plate coated with iron paint, immersed at
Key West, Fla., was found to be covered with branch shell and coral,
but little paint remaining, and very badly pitted and rusted. A plate
with two coats of red lead, at the Norfolk Navy Yard, was found to
have a few barnacles attached, but to be in fair condition, with no
rust whatever on the iron after the paint was removed. It will be seen
that not only did the red lead protect the iron better than the other
pigments referred to, but that the plates were in far better condition
as regards barnacles and fouling. The superiority of red lead being
thus established, it is adopted for use on hulls of U.S. Government
warships.
On the Dutch State railroads a series of experiments extending over a
period of three years were made with the above pigments on scrubbed
plates, as well as those which had been pickled in acid to remove the
scale. It was found that the red lead was superior in each case to the
others.
If red lead is thus proved to be the best pigment for preserving iron
and steel structures, what is the proper method for applying it? We
have seen above that the value of red lead depends upon its forming
certain combinations with the oil, and actually setting very much the
same as plaster of Paris or cement sets when mixed with water. To
successfully work with the latter substances, it is necessary to put
them in shape as quickly as possible after mixing with water before the
setting takes place. If the chemical action of setting has partly taken
place, the material may be moulded, but it is known that good results
will not be obtained. Red lead, like these substances, must be applied
to the work before it sets with the oil. It is on this point that
failures in the use of pigment have generally occurred, because if it
be applied after the combining or setting process has taken place, the
hard, elastic, clinging coating will not be formed on the iron surface.
The following is the practice of one of the largest shipbuilding
establishments in applying red lead to the hulls of vessels. The plates
are first pickled in a dilute solution of muriatic acid; then passed
between rapidly revolving wire brushes, which remove all scale and
dirt, leaving the iron with a bright, smooth surface; then thoroughly
washed with pure water, and rubbed entirely dry; and immediately
coated with red lead and pure raw linseed oil. The red lead is first
thoroughly mixed with just enough linseed oil to form a very thick,
tough paste, which will keep for several days without hardening. This
paste, as wanted for use, is thinned down to the proper consistency for
spreading with pure linseed oil, and applied at once, care being taken
to leave paint-pots empty at night. A gallon of paint thus prepared
contains about 5 lb. of oil and 18 lb. of red lead, and will cover on
first coat about 500 square feet. In this way the red lead and oil
get their initial set on the surface of the iron, and the closer the
pigment is brought to the iron the more durable will it be found. Some
parties prime iron with iron oxide paint or metallic brown before
applying red lead, which appears to be a mistake, as this paint readily
scales from iron, and, of course, carries the lead with it. Others coat
the iron with oil before applying the red lead. This, too, prevents the
adhering paint from coming in contact directly with the surface, and
should be avoided, provided the iron is properly prepared by thorough
cleaning and removal of any scale and moisture, which is a matter of
the greatest importance.
In priming wood surfaces which are absorbent of oil, the best practice
favours the putting on of a coat of pure oil, or oil thinned with
turpentine, which shall penetrate the surface, and form a binder for
the subsequent coats. With iron, the case is quite different, provided
we have a paint which, from its very nature, can attach itself firmly
to the surface, because it is out of the question for it to hold on
to the surface of iron by any process of absorption into the pores of
the metal, as linseed oil will not penetrate to any extent. Such a
paint should be put directly on the surface of the clean, dry metal,
as is done in the cases of Government vessels referred to, without the
intervention of a coat of oil or other substances.
The rusting of iron before the application of paint, which is sometimes
recommended, should by all means be avoided, as it not only prevents
the contact of the paint with the metal, but induces a chemical action
which may go on with its corroding work under the applied paint.
As to the relative cost of iron oxide paints and red lead, there is no
doubt that the first cost of painting structures with iron oxide is
somewhat less than with red lead. The best railroad authorities state,
however, that labour in painting structural work costs twice as much as
material. The true economy must therefore be sought in the durability
of the paint as well as the preservation of the structure from rust.
Actual experiments have shown that structures painted with iron paint
had to be repainted in the third or fourth year, those with red lead
not until the sixth year.
In the second painting with iron paint, the old material must be
entirely removed before a fresh coat can be properly applied, entailing
considerable increased cost, whereas with the red lead no such expense
is necessary, but, as before stated, a portion of the pigment remains
on the iron, continuing to protect the surface, and is the very best
base for the new coat, besides contributing materially towards it,
lessening the expense of each repainting. It will therefore be easily
seen that, although in first cost red lead may be slightly dearer than
the iron paint, yet in the long run it will be greatly cheaper, besides
giving assurance, for the reasons above stated, that the structure is
not deteriorating from the effects of the atmosphere and paint.
Before closing, it might be well to allude to the effect of lampblack
when mixed in small quantities, say an ounce to the pound of red lead.
It changes the colour to a deep chocolate, a possible advantage in
some cases, and also prevents the red lead from taking its initial set
with linseed oil as quickly as when mixed with oil alone. Experiments
recently made showed that this compound would remain mixed in paste
form with linseed oil some thirty days without hardening. Thorough
mixture is of the greatest importance, and should be done in the dry
state before adding the oil. If rapid drying is desired, Japan dryer
can be mixed with the oil used in thinning the paste before application
with the brush.
Too much stress cannot be laid on the great importance of having the
metallic surface perfectly clean and as free as possible from scale
and rust before the application of the paint. Where pickling with acid
is impracticable, as is frequently the case in railroad and other
structural work, thorough brushing with wire brushes should be resorted
to.
FRESCO PAINTING.--The following observations are due to Prof.
Barff, who dealt with the subject in one of the Cantor Lectures given
at the Society of Arts.
The ground upon which fresco is painted is a lime ground; and in order
to have a permanent picture, it is clear we must have a firm and stable
ground. In order to prepare that ground, first of all the wall must be
absolutely dry; there must be no leakage of moisture from behind. Lime
which has been “run” (as it is technically called by builders) for a
year or a year and a half is best to be employed, for in proportion
as the lime has been carbonated (though it must not be so to too great
an extent) by the action of the carbonic acid of the air it makes a
better and a harder mortar. With this lime must be mixed sand, and a
great deal depends on the selection of the sand. It must be river sand,
and it should be of even grain; the sand should be mixed with water,
and allowed to pass along down a small stream, so that in the centre of
the stream you would have sand grains pretty nearly equal in size. This
is a point of considerable importance. The reason why new lime cannot
and ought not to be used is because it blisters; small blisters appear
on the surface, and that of course would be ruinous to a picture. A
well-plastered wall should not have a blister or crack in it, and this
is secured by having your lime run for some time, of good quality to
start with, and mixed with good sand. There is no chemical process that
takes place in fresco painting other than this, that silicates are
formed by the action of the lime upon the sand, and carbonates by the
action of the carbonic acid of the air upon the lime.
In painting a fresco picture, inasmuch as there is no retouching
the work when it is finished, the artist must make his drawing very
carefully. The cartoon is made upon ordinary paper, then it is fixed
against the wall where the picture is to be painted. The part where
the artist decides to begin his work is uncovered, that is to say, a
portion of the paper is turned down and cut away, but in such a manner
that it may be replaced. Then the plasterer puts fresh plaster, about
an eighth of an inch thick, upon the uncovered portion of the wall, and
the plasterer’s work is of the utmost importance in fresco painting.
The workman ought to practise it well before he attempts to prepare
the ground for a large picture, and it is of the greatest importance
to allow the man to practise for several weeks before he is allowed to
prepare any portion of the ground, even for decorative: painting. In
this way he becomes accustomed to the suction of the wall, and upon
the suction of the wall depends the soundness of the ground and the
success of fresco painting.
When the plaster is first put on, of course it is very soft; the piece
of cartoon is replaced upon it, and the lines of the picture are gone
over with a bone point, so that an indentation is made, and then the
artist begins his painting. At first he finds his colours work greasy;
you cannot get the tint to lie on, it works streaky; but you must not
mind that, you must paint on, but you must only paint on for a certain
time, for if you go on painting too long you will interfere with the
satisfactory suction of the ground, which is so necessary to produce a
good fresco painting. Of course, nothing but practice can tell any one
the period at which he ought to stop. After some practice, you know
perfectly well by the feel when you ought to stop. If you feel your
colour flowing from your brush too readily, you ought to stop at this
period. You must then leave your work for a time, and go back to it
again. And then you will find, as the plaster sucks in the colour which
you have first laid on, that there will be--it may be in the course of
half-an-hour, it may be an hour, that depends upon the temperature of
the atmosphere--a pleasant suction from your brush, the colour going
from it agreeably, and you will find that it will cover better. Now
is the time to paint rapidly, and complete the work you have in hand.
When the colour leaves your brush as though the wall was thirsty for
moisture, you should cease painting; every touch that is applied after
that will turn out grey when it dries, and the colour will not be fast
upon the wall.
You will see, then, how impossible it is, with such materials, to
paint in the same style in which you paint a picture in oil-colour.
Fresco painting involves the adoption of an entirely different style
from oil painting. The frescoes of the old masters are not highly
wrought up, highly-finished works. They depend for their effect upon
the juxtaposition of tints, the shadows being intensified by lines and
cross-hatching. If you look at those reproductions of some of the most
valuable fresco paintings of the old masters, you will see the method
adopted by them depended upon the juxtaposition of tints, not upon
covering over, and over, and over again. That juxtaposition of tints
produces roundness, transparency, and has a very pleasing effect upon
the eye. If two tints are put against one another, they do not appear
to us as if they were single, but each adds something to the effect
of the other, and together they produce a pleasurable and agreeable
effect, if they have been properly selected. We all know how tempting
it is to go back to a piece of painting and do something to it that
ought to have been done before. We think that a touch will improve
it, and we go and make it: but in fresco painting the temptation must
be resisted, for it will be absolutely fatal to the permanency of the
work.
INDEX
African indigo, 47
Alkali for removing old paint, 351
Alumina for lakes, 282
American indigo, 47
---- lamp-black furnace, 20
Aniline black, 25
Animal black, 5, 6
---- matters, nitrogen in, 51
Anthracene oil black, 21
Antimony vermilion, 138
Antwerp blue, 62
Area covered by paint, 359, 360
Arnaudon’s green, 128
Arsenic from cobalt ores, 31
---- orange, 153
---- yellow, 257, 280
Asphalt brown, 101
---- for painting iron, 373
Aureolin, 257
Azurite blue, 40
Balmains luminous paint, 286
Baryta blue, 111
---- green, 109
---- red, 143
---- white, 170
Barytes, 170
Benzoates as dryers, 318
Benzol vehicles, 296
Binder’s cobalt blue, 29
Bistre, 101
Bitumen, 101
Blacks, 5-26
---- adulterations, 6
---- aniline, 25
---- animal, 5, 6
---- anthracene oil, 21
---- bone, 5, 6
---- bone-oil, 12
---- candle, 25
---- “carbon,” 19
---- charcoal, 25
---- coal, 25
---- coal tar, 14, 15, 21
---- coke-oven, 16
---- composition, 5
---- cork, 25
---- creosote oil, 21
---- drop, 11
---- fat, 11, 12, 21
---- Frankfort, 11
---- “gas,” 19
---- gas-tar, 14, 15, 21
---- German, 26
---- impurities, 5
---- iron, 26
---- ivory, 5, 11
---- lamp, 5, 11
---- lead, 26
---- manganese, 26
---- mineral gas, 19
---- ---- matter in, 6
---- natural gas, 19
---- oil, 11, 12, 21
---- oily matter in, 5
---- organic, 5
---- paraffin, 16
---- peach-stone, 11
---- Prussian, 26
---- prussiate, 26
---- resin, 11. 15, 16
---- shale oil, 21
---- Spanish, 26
---- tannin, 26
---- tar, 14, 15, 21
---- testing, 6
---- unimportant, 25
---- vegetable, 5, 11, 25, 26
---- vine twig, 11
---- wine lees, 11
Blanc fixe, 172
Bleaching oils, 332
Blenkinsop and Hartley’s dryer, 335
Blood in priming coat, 352
Blue luminous paint, 291
---- potash, 54, 56
---- salt, 54, 56
---- washing, 90
Blues, 27-100
---- Antwerp, 62
---- azurite, 40
---- baryta, 111
---- Binder’s cobalt, 28
---- Bong’s, 62
---- Bremen, 34
---- Brunswick, 64
---- cæruleum, 27
---- Chinese, 65
---- cobalt, 27, 28
---- cœruleum, 37
---- copper, 34
---- indigo, 42
---- lime, 38
---- manganese, 49
---- mountain, 40
---- Paris, 68
---- Péligot, 41
---- Prussian, 49
---- Saxon, 69
---- smalts, 27, 30
---- soluble, 69
---- Thénard’s cobalt, 28
---- Turnbull’s, 70
---- ultramarine, 70
---- verditer, 41
---- zaffre, 30
Body of pigments, 293
Boiled oils, adulterants of, 331
---- ---- defects, 327
---- ---- substitute for, 352
---- ---- testing for lead in, 328
Boiling oil, 316, 320
Bole, 272
Boletta, 273
Bologna stone, 170
Bone black, 5, 6
---- ---- composition, 10
---- cost of production, 10
---- ---- furnaces, 7
---- ---- qualities, 10
---- brown, 102
---- oil black, 12
Bones, carbonising, 7
---- gases from, utilising, 9
Bong’s manganese blue, 49
---- Prussian blue, 62
Borates as dryers, 318
Braconnot’s green, 123
Bramwell’s prussiate, 58
Brazil-wood lake, 283
Bremen blue, 34
---- green, 112
Brighton green, 112
Brinjes and Goodwin’s paint mill, 346
Brown luminous paint, 291
Browns, 101, 108
---- asphalt, 101
---- bistre, 101
---- bitumen, 101
---- bone, 102
---- cappagh, 102
---- Cassel earth, 102
---- chicory, 102
---- Cologne earth, 102
---- manganese, 103
---- Mars, 103
---- Prussian, 103
---- Rubens, 102
---- sepia, 104
---- ulmin, 105
---- ultramarine, 88
---- umbers, 105
---- Vandyke, 107
Brunquell on prussiate, 59
Brunswick blue, 64
---- green, 113
---- ---- characters, 118
---- ---- dry method, 117
---- ---- testing, 118
---- ---- wet method, 115
Brushes, 355
---- keeping, 355
Buckley’s prussiate works, 59
Cadmium Yellow, 258
Cæruleum, 27
Calcining lamp-black, 23
Calcium hyposulphite, preparing, 139
---- polysulphide, preparing, 139
Candle black, 25
Candle-nut oil, 298
Cappagh brown, 102, 106
“Carbon” black, 19
---- pigments, 5
Carbonising bones, 7
Carminated lake, 283
Carmine lake, 283
Carriages, painting, 361
---- varnishing, 365
Cars, painting, 361
---- re-varnishing, 367
---- washing, 367
Cassel earth, 102
Cassius purple, 143
Cawk, 170
Central American indigo, 47
Cerchione, 273
Chalk, 246
Charcoal black, 25
Charlton white, 172, 254
Chicory brown, 102
China clay, 172
---- ---- artificial, 182
---- ---- characters, 182
---- ---- drying, 175, 181
---- ---- waste products, 179
---- ---- works, 173
Chinese blue, 65
---- green, 118, 129
---- red, 144, 185
---- vermilion, 157
Chromates, iron, 267
---- lead, 260
---- zinc, 268
Chrome greens, 113, 118, 125
---- orange, 144
---- red, 144, 145
---- yellows, 258
Chromes, characters, 266
Clark’s paint mill, 341
Coaches, painting, 361
---- re-varnishing, 367
---- varnishing, 365
---- washing, 367
Coal black, 25
Coal-tar black, 14, 15, 21
Coats of paint, 355
Cobalt benzoate, 318
---- blues, 27, 28
---- borate, 318
---- greens, 119
---- ore furnace, 31
---- oxide blue, 28
---- pink, 144
---- red, 144
Cochineal lake, 284
Cœruleum blue, 37
Coke oven black, 16
Colcothar, 145, 150
Cologne earth, 102
Colour and aggregation of particles, 2
---- ---- chemical composition, 2
---- ---- light, 1
---- causes, 1
---- defined, 1
---- destruction, 2
---- of pigments, testing, 293
---- sense, 1
Condenser, fume, 216
Condensing smoke, 13, 15, 17
Condy’s white lead, 197
Copper blues, 34
---- carbonate, 40
---- greens, 121, 130, 131
---- hydrated oxide, 34, 41
---- nitrate, 36
---- sulphate dryer, 325
Cork black, 25
Cornish umber, 107
Cotton seed oil in linseed oil, 301
Covering power of pigments, 293
Cracking, causes, 363
Creosote oil black, 21
Crucibles for roasting smalts, 32
Cuttle fish brown, 104
Cyanogen in prussiate making, 58
Cyprus earth, 134
Dammar vehicles, 296
Derby red, 145
Derbyshire umber, 106
Discoloration of paint, 356
Douglas green, 120
Drop black, 11
Dryers, 295-338, 365
Dryers, benzoates, 318
---- Blenkinsop and Hartley’s, 335
---- borates, 318
---- chemical action of, 322
---- ---- ---- in oils, 330
---- cobalt benzoate, 318
---- copper sulphate, 325
---- Guynemer’s, 319
---- lead, 325
---- litharge, 316
---- manganese benzoate, 318
---- ---- oxalate, 319
---- ---- oxide, 318
---- ---- sulphate, 325
---- red lead, 316
---- resinates, 318
--- zumatic, 318
Drying china clay, 175, 181
---- paint, 353, 367
---- white lead, 191
Durability of pigments, 294
Dutch vermilion, 167
---- white lead, 185
Dyestuff defined, 1, 3
Egyptian cœruleum, 37
Emerald green, 121
---- ---- characters, 124
---- ---- testing, 124
---- tint greens, 124
Enamel white, 245, 254
Enamelled white, 170, 183
English white, 183, 246
Extraction of oils, 308
Eye, colour effect on, 1
Fascia, 273
Fat-black, 11, 12, 21
Ferric oxide reds, 150
Figuier’s red, 144
Filling before painting, 354, 362
Fineness of pigments, testing, 293
Finishing painting, 363
Firmenich’s vermilion, 165
Fleck’s vermilion, 156
Frankfort black, 11
Freeman’s white, 224, 254
French and Hannay’s white lead, 216
Fresco colours, 257
---- painting, 111, 378
Fume condenser, 216
Furnaces, bone-black, 7
---- cobalt ore, 31
---- galena, 225
---- lamp-black, 12, 14, 16, 17, 18, 19, 20, 21
---- ochre, 277
---- prussiate, 53, 59, 60
---- smalts, 32, 33
Galena, chromates from, 263
---- white lead from, 225
Galloway’s green, 123
Gamboge, 270
Gardner’s white lead, 200
“Gas” black, 19
Gases from bones, utilising, 9
Gas-tar black, 14, 15, 21
Gaud indigo, 45
German black, 26
---- lamp-black, 15
Gmelin’s ultramarine, 81
Green luminous paint, 291
Greens, 109
---- Arnaudon’s, 128
---- baryta, 109
---- Braconnot’s, 123
---- Bremen, 112
---- Brighton, 112
---- Brunswick, 113
---- Chinese, 118, 129
---- chrome, 113, 118, 125
---- cobalt, 119
---- copper, 121, 130, 131
---- Cyprus earth, 134
---- Douglas, 120
---- emerald, 121
---- ---- tint, 124
---- Galloway’s, 123
---- Guignet’s, 125
---- Köchlin’s, 123
---- lokao, 129
---- malachite, 129, 131
---- manganese, 130
---- mineral, 130, 131
---- mitis, 130
---- mountain, 131
---- Paris, 132
---- Prussian, 132
---- Rinmann’s, 132
---- sap, 129, 132
---- Scheele’s, 133
---- Schweinfurth, 134
---- terre verte, 134
---- titanium, 135
---- ultramarine, 73
---- verdigris, 135
---- verditer, 136
---- Verona earth, 134, 136
---- Victoria, 137
---- Vienna, 137
---- zinc, 137
Grey luminous paint, 291
Griffith’s zinc white, 251
Grinding Chinese blue, 67
---- smalts, 34
Ground-nut oil, 297
Guignet’s green, 125
Guimet’s ultramarine, 81
Guynemer’s dryer, 319
Gypsum, 183
Hannay’s white lead, 214
Hartley & Blenkinsop’s dryer, 335
---- on dryers, 322
Hempseed oil, 298
Hind and Lund’s paint mill, 345
Hyposulphite of lime, preparing, 139
Idrian vermilion works, 154
Indian indigo, 43
---- red, 147, 150
Indigo, African, 47
---- American, 47
---- blue, 42
---- carmine, 48
---- Central American, 47
---- cultivation, 43
---- gaud, 45
---- Indian, 43
---- Japanese, 45
---- Javan, 46
---- maceration, 43
---- manufacture, 43
---- Philippine, 47
---- plants, 42
---- preparations, 48
---- qualities, 48
---- testing, 48
Irish umber, 106
Iron black, 26
---- chromates, 267
---- decay, 369
---- oxide for painting, 373
---- ---- reds, 150
---- painting, 369
---- ---- experiments, 375
---- pitching, 369
Italian white lead, 221
Ivory black, 5, 11
Jacquelin’s vermilion, 168
Japanese indigo, 45
Javan indigo, 46
Kaolin, 172, 183
Keeping brushes, 355
Kegs, paint, 349
Kilns, 7, 12, 14, 16, 17, 18, 19, 20, 21, 31, 32, 33, 53, 59, 60, 225, 277
King’s yellow, 271, 280
Kirchoff’s vermilion, 168
Köchlin’s green, 123
Kukui oil, 298
Lakes, 282
---- alumina, 282
---- Brazil-wood, 283
---- carminated, 283
---- carmine, 283
---- cochineal, 284
---- madder, 284
---- yellow, 285
Lamp-black, 5, 11
---- ---- anthracene oil, 21
---- ---- apparatus, 12, 14, 15, 16, 17, 19, 20, 21, 22
---- ---- calcining, 23
---- ---- creosote oil, 21
---- ---- gas tar, 14, 15, 21
---- ---- German, 15
---- ---- in iron painting, 378
---- ---- Martin & Grafton’s, 15
---- ---- natural gas, 19
---- ---- nuisance in making, 23
---- ---- paraffin, 16
---- ---- qualities, 25
---- ---- Russian, 16
---- ---- Shackell & Edwards’ Works, 24
---- ---- shale oil, 21
---- ---- transport, 25
Lapis lazuli, 70
Lead black, 26
---- chromates, 260
---- dryers, 325
---- for white lead making, 186
---- in boiled oil, testing for, 328
---- orange, 147
---- red, 148
---- sulphate, 223
---- whites, 183
Levigating ultramarine, 79
Lewis’s white lead, 223
Light and colour, 1
Lime blue, 38
---- hyposulphite, preparing, 139
---- manganate, 49
---- polysulphide, preparing, 139
---- white, 170, 245
Linseed oil, 299
---- ---- adulterants, 331
---- ---- bleaching, 303
---- ---- impurities, 301
---- ---- purifying, 302
Litharge as a dryer, 316
Lithophone, 245, 247
Lokao, 129
Luminous paints, 286
MacIvor’s ultramarine, 93
---- white lead, 229
Madder, lake, 284
Magnesite, 245
Malachite green, 129, 131
Manganese benzoate, 318
---- black, 26
---- blue, 49
---- borate, 318
---- brown, 103
---- green, 130
---- linoleate, 336
---- oxalate dryer, 319
---- oxide dryer, 318
---- sulphate dryer, 325
Manure from prussiate residue, 57
Mars brown, 103
Martin & Grafton’s lamp-black, 15
Massicot, 148
Measuring painting, 360
Menhaden oil, 303
Metallic paints, 274
Mica, 179
Mills, oil, 309
---- paint, 339, 341, 345, 346
Mineral gas black, 19
---- green, 130, 131
---- matter in blacks, 6
---- orange, 150
Minium, 148
Mitis green, 130
Mixer for paint, 341
Mixing paint, 364
Mountain blue, 40
---- green, 131
Murdoch’s antimony red, 142
Naples yellows, 271
Natural gas black, 19
Nitrogen converted into cyanogen in prussiate making, 58
---- in animal matters, 51
Nuisance from making lamp-black, 23
---- prevention, 24
Ochres, 272
---- characters, 279
---- kilns, 277
---- working, 274
Odour of paint, removing, 356
Oil-black, 11, 12, 21
---- cake, moulding, 313
---- mill, 309
---- seed crushing rolls, 311
---- ---- kettles, 312
---- vehicles, 295
Oils, bleaching, 332
---- boiled, defects, 327
---- ---- substitute for, 352
---- ---- testing for lead in, 328
---- boiling, 316, 320
---- ---- chemistry of, 326
---- candle-nut, 298
---- chemical action of dryers on, 330
---- drying and non-drying, 297
---- extraction, 308
---- ground-nut, 297
---- hemp-seed, 298
---- kukui, 298
---- linseed, 299
---- menhaden, 303
---- pea-nut, 297
---- poppy, 305
---- porgie, 303
---- refining, 335
---- tobacco, 306
---- tung, 308
---- walnut, 307
---- wood, 308
Oily matter in blacks, 5
Old paint, removing, 351
Orange, chrome, 144
---- lead, 147
---- luminous paint, 291
---- mineral, 150
Organic blacks, 5
Orpiment, 280
Orr’s white, 245, 254
Oxide reds, 150
Oxygen in making ultramarine, 78
Packing paint, 349
Paint beds, 274
---- composition, 358
---- covering power, 359, 360
---- cracking, 363
---- defined, 1
---- discoloration, 356
---- drying, 367
---- estimating quantity required, 359, 360
---- machinery, 339
---- mills, 339, 341, 345, 346
---- mixer, 341
---- mixing, 364
---- old, removing, 351
---- packing, 349
---- priming, 354, 362
Painting, 351
---- brushes, 355
---- carriages, 361
---- coats, 355
---- drying, 353
---- filling, 354, 362
---- finishing, 363
---- fresco, 378
---- iron, 369
---- measuring, 360
---- plaster, 378
---- priming coat, 352, 362
---- removing odour, 356
---- surface, 351
---- walls, 378
---- water-colours, 356
---- woodwork, 368
Paraffin black, 16
---- wax vehicles, 296
Paris blue, 68
---- green, 132
--- white, 246
Peach-stone black, 11
Pea-nut oil, 297
Péligot blue, 41
Permanent white, 170, 246
Persian red, 145, 150, 153
Philippine indigo, 47
Phosphorescent paints, 286
Pigments, carbon, 5
---- defined, 1, 3
---- examining, 293
---- requirements, 3
---- testing body, 293
---- ---- colour, 293
---- ---- covering power, 293
---- ---- fineness, 293
Pink, cobalt, 144
Pitching iron, 369
Plaster painting, 378
Pompeian cœruleum, 37
Poppy seed oils, 305
Porgie oil, 303
Potash, blue, 54, 56
---- prussiate, 50
Prevention of nuisance, 24
Priming coat, 352
---- paint, 362
Prussian black, 26
---- blue, 49
---- ---- Bong’s, 62
---- ---- common, 61
---- ---- qualities, 49
---- ---- recipes, 61
---- ---- testing, 50
---- brown, 103
---- green, 132
Prussiate, 50
---- black, 26
---- Bramwell’s works, 58
---- Brunquell on, 59
---- Buckley’s works, 59
---- crystallisation, 55
---- formation, 52
---- furnaces, 53, 59, 60
---- metal, lixiviation, 55
---- of potash, 50
---- pots, 53
---- residue as manure, 57
---- separating: impurities, 56
Pug mill, 341
Purple of Cassius, 143
Putty, 354, 362
Puttying, 354, 362
Realgar, 153, 280
Red lead, 148
---- ---- as a dryer, 316
---- ---- for painting iron, 374
---- luminous paint, 291
---- ultramarine, 77, 80
Reds, 138-169
---- antimony vermilion, 138
---- baryta, 143
---- Cassius purple, 143
---- Chinese, 144, 145
---- chrome, 144, 145
---- ---- orange, 144
---- cobalt, 144
---- ---- pink, 144
---- colcothar, 145, 150
---- Derby, 145
---- Indian, 147, 150
---- iron oxide, 150
---- lead orange, 147
---- minium, 148
---- orange mineral, 150
---- oxides, 150
---- Persian, 145, 150, 153
---- realgar, 153
---- rouge, 150, 153
---- tin, 144
---- Venetian, 150, 153
---- vermilion, 153
Refining oils, 335
Removing old paint, 351
Resin black, 11, 15, 16
Resinates as dryers, 318
Rinmann green, 132
Roller mills for paint, 339, 341, 345, 346
Rosin in linseed oil, 301
Rouge, 150, 153
Rubens brown, 102
Ruby of arsenic, 153
Russian lamp-black, 16
Rutherford & Barclay kiln, 277
Sap green, 129, 132
Satin white, 246
Saxon blue, 69
Schatte’s luminous paint, 290
Scheele’s green, 133
Schweinfurth green, 134
Seed-crushing rolls, 311
---- kettles, 312
---- oils, extracting, 308
Sepia, 104
Shackle and Edwards’ lamp-black works, 24
Shale oil black, 21
Ships’ hulls, painting, 376
Siena earths, 272
Siennas, 272
Silica ultramarine, 74
Smalts, 27, 30
---- crucibles, 32
---- furnace, 32, 33
---- grinding, 34
Smith’s pitching process for iron pipes, 369
Smoke, condensing, 13, 15, 17
Soda for making ultramarine, 78, 92
---- sulphate from ultramarine, 79
---- ultramarine, 74
Soluble blue, 69
Spanish black, 26
---- white, 246
Square blue, 90
Stack white lead, 185
Stampshaw lamp-black furnace, 21
Stangen-spath, 170
Strontia white, 246
Sulphate ultramarine, 72
Surface for painting, 351
Tannin black, 26
Tar black, 14, 15, 21
Terra alba, 183, 246
---- bolare, 273
---- guilla, 273
Terre verte, 134
Thalwitzer’s lamp-black apparatus, 16
Thénard’s cobalt blue, 28
---- white lead, 184
Tin red, 144
Titanium green, 135
Tobacco-seed oil, 306
Transport, lamp-black, 25
---- paint, 349
Tung oil, 308
Turkey umber, 106
Turnbull’s blue, 70
Ulmin, 105
Ultramarine, 70
---- adulterations, 76
---- ancient treatise on, 94
---- artificial, 71
---- brown, 88
---- Brunner on, 82
---- chemistry, 81
---- colouring principle, 75
---- composition, 81
---- direct crucible process, 87
---- Dollfus on, 84
---- effect of silica, 83
---- Endemann on, 82
---- faults, 100
---- German process, 86
---- Gmelin’s, 81
---- Goppelsröder on, 84
---- green, 73
---- Guimet’s, 81
---- Heyne on, 94
---- history, 80
---- Hoffmann on, 83
---- indirect process, 85
---- levigating, 79
---- Leykauf process, 94
---- McIvor’s, 93
---- natural, 70
---- Nejedly on, 94
---- oxygen in making, 78
---- properties, 76
---- red, 77, 80
---- removing soluble salts, 78
---- resisting alum, 75, 77
---- Ritter on, 82
---- Schülzenberger on, 82
---- silica process, 74
---- soda for, 78, 92
---- ---- process, 74
---- ---- sulphate from, 79
---- statistics, 91
---- Stein on, 81
---- sulphate process, 72
---- testing, 99
---- uses, 76, 90, 99, 100
---- varieties, 99
---- violet, 77, 79
---- Wilkins on, 81
Umbers, 105, 272
Vandyke brown, 107
Varnishing coaches, 365, 367
Vegetable blacks, 5, 11, 25, 26
Vehicles, 295-338, 365
Venetian red, 150, 153
Verdegris, 135
Verditer, 136
---- blue, 41
Vermilion, 153
---- antimony, 138
---- Chinese, 157
---- Dutch, 167
---- Firmenich’s, 165
---- Fleck’s, 156
---- Jacquelin’s, 168
---- Kirchoff’s, 168
---- Weshle’s, 168
---- works at Idria, 154
Verona earth, 134, 136
Victoria green, 137
Vienna green, 137
Vine-twig black, 11
Violet luminous paint, 291
---- ultramarine, 77, 79
Wagner’s antimony red, 142
Wall painting, 378
Walnut oil, 307
Washing blue, 90
Water-colour painting, 356
Wax vehicles, 296
Weshle’s vermilion, 168
Wetherill furnace, 225
White lead, 183
---- ---- adulterations, 195
---- ---- characters, 242
---- ---- chemistry of, 187, 192, 193, 200
---- ---- Condy’s, 197
---- ---- cost, 213
---- ---- dangers of, 191
---- ---- dry, 195
---- ---- drying, 191
---- ---- Dutch, 185
---- ---- French & Hannay’s, 216
---- ---- from galena, 225
---- ---- Gardner’s, 200
---- ---- Hannay’s, 214
---- ---- Italian, 221
---- ---- lead for, 186
---- ---- Lewis’s, 223
---- ---- MacIvor’s, 229
---- ---- powdered, 195
---- ---- precipitated, 194
---- ---- stack, 185
---- ---- substitutes, 194
---- ---- testing, 244
---- ---- Thénard’s, 184
---- luminous paint, 286, 290
Whites, 170-256
---- baryta, 170
---- blanc fixe, 172
---- chalk, 246
---- Charlton, 172, 254
---- china clay, 172
---- enamel, 245, 254
---- enamelled, 170, 183
---- English, 183, 246
---- Freeman’s, 224, 254
---- Griffith’s, 251
---- gypsum, 183
---- lead, 183
---- lime, 170, 245
---- lithophone, 245, 247
---- magnesite, 245
---- mineral, 183, 245
---- Orr’s, 245, 254
---- Paris, 246
---- permanent, 170, 246
---- satin, 246
---- Spanish, 246
---- strontia, 246
---- terra alba, 183, 246
---- whiting, 246
---- zinc, 247
Whiting, 246
Wilson’s fume condenser, 216
Wine-lees black, 11
Wood charcoal black, 25
-- oil, 308
Woodwork, painting, 368
Working ochre beds, 274
Wright’s paint machinery, 339
Yellow luminous paint, 291
---- prussiate, 50
Yellows, 257-281
---- arsenic, 257, 280
---- aureolin, 257
---- hole, 272
---- cadmium, 258
---- chrome, 258
---- gamboge, 270
---- King’s, 271, 280
---- lakes, 285
---- Naples, 271
---- ochres, 272
---- orpiment, 280
---- realgar, 280
---- umbers, 272
Zaffre, 30
Zinc chromates, 268
---- green, 137
---- oxide, 37, 247
---- sulphide, 250
---- whites, 247
---- ---- characters, 255
Zumatic dryer, 318
LONDON: PRINTED BY WILLIAM CLOWES AND SONS, LIMITED, STAMFORD STREET
AND CHARING CROSS.
End of Project Gutenberg's Pigments, Paint and Painting, by George Terry