CONTENTS.

INTRODUCTION, xi.

RESEARCH I.

_Into the analysis of_ NITRIC ACID _and_ NITROUS GAS,

_and the production of_ NITROUS OXIDE.

DIVISION I.

EXPERIMENTS _and_ OBSERVATIONS _on the composition

of_ NITRIC ACID, _and on its combinations with_

WATER _and_ NITROUS GAS.

1. Preliminaries 1

2. Production of aëriform Nitrous Acid 3

3. Specific gravity of Gases 6

4. Experiment on the formation of Nitrous Acid 11

5. Conclusions 17

6. Experiments on the combination of Nitrous Gas

with Nitric Acid 17

7. Additional Experiments 23

8. Conclusions 29

9. Mr. THOMSON’S Theory of the difference

between Nitric and Nitrous Acid 30

10. Composition of the different Nitrous Acids 36

11. Combination of Nitric Acid with Water 38

12. Of Nitrous Vapor 42

13. Comparison of the results with those of

Cavendish and Lavoisier 43

DIVISION II.

EXPERIMENTS _and_ OBSERVATIONS _on the composition

of_ AMMONIAC _and on its combinations with_ WATER

_and_ NITRIC ACID.

1. Analysis of Ammoniac 56

2. Specific gravity of Ammoniac 62

3. Of the quantities of true Ammoniac in

Ammoniacal Solutions 65

4. Composition of Nitrate of Ammoniac 71

5. Decomposition of Carbonate of Ammoniac,

by Nitrous Acid 75

6. Decomposition of Sulphate of Ammoniac by Nitre 77

7. Non-existence of Ammoniacal Nitrites 79

8. Sources of error in Analysis 80

9. Loss in Solutions of Nitrate of Ammoniac

during evaporation 83

DIVISION III.

DECOMPOSITION _of_ NITRATE _of_ AMMONIAC—_Preparation

of_ RESPIRABLE NITROUS OXIDE.

1. Of the heat required for the decomposition of

Nitrate of Ammoniac 84

2. Decomposition of Nitrate of Ammoniac—Production

of respirable Nitrous Oxide—its properties 86

3. Of the Gas remaining after the absorption of

Nitrous Oxide by Water 89

4. Specific Gravity of Nitrous Oxide 94

5. Analysis of Nitrous Oxide 95

6. Minute examination of the decomposition

of Nitrate of Ammoniac 101

7. Of the heat produced during the decomposition

of Nitrate of Ammoniac 108

8. Decomposition of Nitrate of Ammoniac at

high temperatures 109

9. Speculations on the decompositions of Nitrate

of Ammoniac 113

10. Of the preparation of Nitrous Oxide for

experiments on respiration 117

DIVISION IV.

EXPERIMENTS _and_ OBSERVATIONS _on the composition of_

NITROUS GAS, _and on its absorption by different

bodies_.

1. Preliminaries 122

2. Analysis of Nitrous Gas by Charcoal 126

3. Analysis of Nitrous Gas by Pyrophorus 132

4. Additional observations on the composition of

Nitrous Gas 134

5. Absorption of Nitrous Gas by Water 140

6. Absorption of Nitrous Gas by Water of

different kinds 147

7. Absorption of Nitrous Gas by solution of

pale green Sulphate of Iron 152

8. Absorption of Nitrous Gas by solution of

green muriate of Iron 179

9. By Solution of Nitrate of Iron 187

10. By other metallic Solutions 189

11. Action of sulphurated Hydrogene on solution

of green sulphate of iron impregnated with

Nitrous Gas 191

12. Additional Observations 193

DIVISION V.

EXPERIMENTS _and_ OBSERVATIONS _on the production of_

NITROUS OXIDE _from_ NITROUS GAS _and_ NITRIC ACID

_in different modes_.

1. Preliminaries 197

2. Conversion of Nitrous Gas into Nitrous Oxide

by alkaline sulphites 199

3. By Muriate of Tin 202

4. By Sulphurated Hydrogene 203

5. Decomposition of Nitrous Gas by Nascent

Hydrogene 206

6. Miscellaneous Observations 209

7. Recapitulation 211

8. Production of Nitrous Oxide from Metallic

Solutions 213

9. Additional Observations relating to the

production of Nitrous Oxide 219

10. Decomposition of Aqua regia by platina,

and evolution of a gas analogous to oxygenated

muriatic acid, and nitrogene 222

11. Action of the electric spark on a mixture

of Nitrogene and Nitrous gas 229

12. General remarks on the production

of Nitrous Oxide 231

RESEARCH II.

_Into the combinations of_ NITROUS OXIDE,

_and its decomposition_.

DIVISION I.

EXPERIMENTS _and_ OBSERVATIONS _on the combinations

of_ NITROUS OXIDE.

1. Combination of Water with Nitrous Oxide 235

2. —— of Nitrous Oxide with fluid inflammable

bodies 240

3. Action of fluid Acids on Nitrous Oxide 244

4. —— of Saline Solutions 245

5. —— of Gases 248

6. Action of aëriform Nitrous Oxide on the

alkalies—History of the discovery of the

combinations of Nitrous Oxide, with the

alkalies 254

7. Combination of Nitrous Oxide with Potash 262

8. Combination of Nitrous Oxide with Soda 268

9. —— —— —— with Ammoniac 269

10. Probability of forming compounds of

Nitrous Oxide and the alkaline earths 273

11. Additional Observations 274

12. The properties of Nitrous oxide resemble

those of Acids 276

DIVISION II.

_Decomposition of_ NITROUS OXIDE _by combustible Bodies_.

1. Preliminaries 278

2. Conversion of Nitrous Oxide into Nitrous Acid

and a gas analogous to Atmospheric Air

by ignition 279

3. Decomposition of Nitrous Oxide by Hydrogene 286

4. —— —— —— by Phosphorus 293

5. —— —— by Phosphorated Hydrogene 300

6. —— —— by Sulphur 303

7. —— —— by Sulphurated Hydrogene 306

8. —— —— by Charcoal 311

9. —— —— by Hydrocarbonate 313

10. Combustion of Iron in Nitrous Oxide 316

11. —— of Pyrophorus 318

12. —— of the Taper 319

13. —— of different Compound Bodies 321

14. General Conclusions relating to the

decomposition of Nitrous Oxide, and

to its analysis 322

15. Observations on the combinations of Oxygene

and Nitrogene 325

RESEARCH III.

_Relating to the_ RESPIRATION _of_ NITROUS OXIDE

_and_ OTHER GASES.

DIVISION I.

EXPERIMENTS _and_ OBSERVATIONS _on the effects produced

upon Animals by the respiration of_ NITROUS OXIDE.

1. Preliminaries 333

2. On the respiration of Nitrous Oxide by

warm-blooded Animals 336

3. Effects of the respiration of Nitrous Oxide

upon Animals, as compared with those produced

by their immersion in Hydrogene and Water 343

4. Of the changes effected in the organisation of

warm-blooded Animals, by the respiration of

Nitrous Oxide 347

5. Of the respiration of mixtures of Nitrous Oxide

and other Gases, by warm-blooded Animals 358

6. Recapitulation of facts relating to the

respiration of Nitrous Oxide, by warm-blooded

Animals 360

7. Of the respiration of Nitrous Oxide,

by amphibious Animals 362

8. Effects of Solution of Nitrous Oxide on Fishes 366

9. Effects of Nitrous Oxide on Insects 370

DIVISION II.

_Of the changes effected in_ NITROUS OXIDE

_and other Gases, by the Respiration of Animals_.

1. Preliminaries 373

2. Absorption of Nitrous Oxide by Venous Blood 374

3. Of the changes effected in Nitrous Oxide

by Respiration 388

4. Respiration of Hydrogene 400

5. Additional Observations and Experiments on the

Respiration of Nitrous Oxide 411

6. Of the Respiration of Atmospheric Air 429

7. Respiration of Oxygene 439

8. Observations on the changes effected in the

blood by Atmospheric Air and Oxygene 445

9. Observations on the Respiration of Nitrous Oxide 449

RESEARCH IV.

_Relating to the_ EFFECTS _produced by the_

RESPIRATION _of_ NITROUS OXIDE

_upon different_ INDIVIDUALS.

DIVISION I.

HISTORY _of the Discovery_.—EFFECTS _produced

by the Respiration of different_ GASES.

1. Respirability of Nitrous Oxide 456

2. Effects of Nitrous Oxide 458

3. General Effects of Nitrous Oxide on the Health 464

4. Respiration of Hydrogene 466

5. —— of Nitrogene 467

6. Effects of Hydrocarbonate 468

7. —— of Carbonic Acid 472

8. —— of Oxygene 473

9. —— of Nitrous Gas 475

10. Most extensive action of Nitrous Oxide

produces no debility 485

DIVISION II.

DETAILS _of the Effects produced by the Respiration

of_ NITROUS OXIDE _upon different Individuals,

furnished by Themselves_.

1. Detail of Mr. J. W. Tobin 497

2. —— of Mr. W. Clayfield 502

3. Letter from Dr. Kinglake 503

4. Detail of Mr. Southey 507

5. Letter from Dr. Roget 509

6. Letter from Mr. James Thomson 512

7. Detail of Mr. Coleridge 516

8. —— of Mr. Wedgwood 518

9. —— of Mr. G. Burnet 520

10. —— of Mr. T. Pople 521

11. —— of Mr. Hammick 522

12. —— of Dr. Blake 524

13. —— of Mr. Wanfey 525

14. —— of Mr. Rickman 526

15. —— of Mr. Lovell Edgworth 527

16. —— of Mr. G. Bedford 528

17. —— of Miss Ryland 530

18. Letter from Mr. M. M. Coates 530

DIVISION III.

_Abstracts from additional Details—Observations on

the effects of_ NITROUS OXIDE,

_by_ Dr. BEDDOES—_Conclusion_.

1. Abstracts from additional details 533

2. Of the effects of Nitrous Oxide on

delicate females 537

3. Observations on the effects of Nitrous Oxide

by Dr. BEDDOES 541

4. Conclusion 548

APPENDIX.

No. I. Of the effects of Nitrous Oxide

on Vegetables 561

No. II. Table of the Weight and Composition

of the combinations of Nitrogene 566

No. III. Additional Observations 567

No. IV. Description of a Mercurial Airholder,

and Breathing Machine,

by Mr. W. CLAYFIELD. 573

No. V. Proposals for the Preservation of

Accidental Observations in Medicine.

By Dr. BEDDOES. 577

Researches Chemical and Philosophical; Chiefly concerning nitrous oxide or dephlogisticated nitrous air and its respiration · 第 2 / 136 题