CHAPTER IV.

Description of Colour Patch Apparatus--Rotating Sectors--Method of

making a Scale for the Spectrum.

Before proceeding further we must describe somewhat in detail two or

three pieces of apparatus to be used in the experiments we shall make.

The first piece was devised by the writer a few years ago, and has got

rid of several objections which existed in older pieces of apparatus. It

is not only useful for lecture purposes, but also for careful laboratory

work. The ordinary lecture apparatus for throwing a spectrum on the

screen is of too crude a form to be effective for the purpose we have in

view; the purity of the colours seen on the screen is more than

doubtful, and this alone unfits it for our experiments. If we want to

form a pure spectrum we must have a narrow slit, prisms with true, flat

surfaces, and lenses of proper curvature. As a rule the ordinary

lecture apparatus for forming the spectrum lacks all of these

requisites.

Fig. 6.--Colour Patch Apparatus.

The accompanying diagram (Fig. 6) will give an idea of the apparatus we

shall employ. On the usual slit S1 of a collimator C is thrown, by means

of a condensing lens L1, a beam of light, which emanates from the

intensely white-hot carbon positive pole of the electric light. The

focus is so adjusted that an image of the crater is formed on the slit.

The collimating lens L2 is filled by this beam, and the rays issue

parallel to one another and fall on the prisms P1 and P2, which

disperse them. The dispersed beam falls on a corrected photographic

lens L3, attached to a camera in the ordinary way. It is of slightly

larger diameter than the height of the prisms, and a spectrum is

formed on the focusing-screen D, which is slewed at a slight angle with

the perpendicular to the axis of the lens L3. This is necessary, because

the focus of the least refrangible or red rays is longer than that of

the more refrangible or blue rays. By slewing the focusing-screen as

shown, a very good general focus for every ray may be obtained. When

the focusing-screen is removed, the rays form a confused patch of

parti-coloured light on a white screen F, placed some four feet off the

camera. The rays, however, can be collected by a lens L4, of about two

feet focus, placed near the position of the focusing-screen, and

slightly askew. This forms an image on the screen of the near surface of

the last prism P2; and if correctly adjusted, the rectangular patch of

light should be pure and without any fringes of colour. The card D

slides into the grooves which ordinarily take the dark slide. In it

will be seen a slit S2, the utility of which will be explained later on.

We shall usually require a second patch of white light, with which to

compare the first patch. Now, although the light from the positive pole

of the carbons is uniform in quality, it sometimes varies in quantity,

as it is difficult to keep its image always in exactly the centre of the

slit. If we can take one part of the light coming through the slit to

form the spectrum, and another part to form the second patch of white

light, then the brightness of the two will vary together. At first sight

this might appear difficult to attain; but advantage is taken of the

fact that from the first surface of the first prism P1 a certain amount

of light is reflected. Placing a lens L5, and a mirror G, in the path of

this reflected beam, another square patch of light can be thrown on the

same screen as that on which the first is thrown, and this second patch

may be made of the same size as the first patch, if the lens L5 be of

suitable focus, and it can be superposed over the first patch if

required; or, as is useful in some cases, the two patches may be placed

side by side, just touching each other.

We are thus able to secure two square white patches upon the screen F,

one from the re-combination of the spectrum, and one from the reflected

beam. If a rod be placed in the path of these two beams when they are

superposed, each beam will throw a shadow of the rod upon the screen.

The shadow cast by the integrated spectrum will be illuminated by the

reflected beam, and the shadow cast by the latter will be illuminated by

the former. In fact we have an ordinary Rumford photometer, and the two

shadows may be caused to touch one another by moving the rod towards or

from the screen. When the illumination of the two shadows by the white

light is equal, the whole should appear as _one_ unbroken gray patch. To

prevent confusion to the eye a black mask is placed on the screen F with

a square aperture cut out of it, on which the two shadows are caused to

fall. If it be desired to diminish the brightness of either patch, it

can be accomplished by the introduction of rotating sectors M, which can

be opened and closed at pleasure during rotation, in the path of one or

other of the beams.

Fig. 7.--Rotating Sectors.

The annexed figure (Fig. 7) is a bird's-eye view of the instrument. A A

are two sectors, one of which is capable of closing the open aperture by

means of a lever arrangement C, which moves a sleeve in which is fixed a

pin working in a screw groove, which allows the aperture in the sectors

to be opened and closed at pleasure during their revolution; D is an

electro-motor causing the sectors to rotate. To show its efficiency, if

two strips of paper, one coated with lamp-black and the other white, are

placed side by side on the screen, and if one shadow from the rod falls

on the white strip, and the other shadow on the black strip of paper,

and the rotating sectors are interposed in the path of the light

illuminating the shadow cast on the white strip, the aperture of the

sectors can be closed till the white paper appears absolutely blacker

than the black paper. White thus becomes darker than lamp-black, owing

to the want of illumination. This is an interesting experiment, and we

shall see its bearings as we proceed, as it indicates that even

lamp-black reflects a certain amount of white or other light.

Having thus explained the main part of the apparatus with which we shall

work, we can go on and show how monochromatic light of any degree of

purity can be produced on the screen. If the slit in the cardboard slide

D be passed through the spectrum when it has been focused on the

focusing-screen, only one small strip of practically monochromatic light

will reach the screen, and instead of the white patch on the screen we

shall have a succession of coloured patches, the colour varying

according to the position the slit occupies in the spectrum. It should

be noted that the purity of the colour depends on two things--the

narrowness of the slit S1 of the collimator, and of the slit S2 in the

card. If two slits be cut in the card D, we shall have two coloured

patches overlapping one another, and if the reflected beam falls on the

same space we shall have a mixture of coloured light with white light,

and either the coloured light or the white light can be reduced in

brightness by the introduction of the rotating sectors. If the rod be

introduced in the path of the rays we shall have two shadows cast, one

illuminated with coloured light, monochromatic or compound, and the

other with white light, and these can be placed side by side, and

surrounded by the black mask as before described.

Fig. 8.--Spectrum of Sodium Lithium and Carbon.

There is one other part of the apparatus which may be mentioned, and

that is the indicator, which tells us what part of the spectrum is

passing through the slit. Just outside the camera, and in a line with

the focusing-screen, is a clip carrying a vertical needle. A small beam

of light passes outside the prism P1; this is caught by a mirror

attached to the side of the apparatus, and is reflected so as to cast a

shadow of the needle on to the back of the card D, on which a carefully

divided scale of twentieths of an inch is drawn. To fix the position of

the slit the poles of the electric light are brushed over with a

solution of the carbonates of sodium and lithium in hydrochloric acid,

and the image of the arc is thrown on the slit. This gets rid of the

continuous spectrum, and only the bright lines due to the incandescent

vapours appear on the focusing-screen (Fig. 8). Amongst other lines we

have the red and blue lines due to the vapour of lithium; the orange,

yellow (D), and green lines of sodium, together with the violet lines of

calcium (these last due to the impurities of the carbons forming the

poles). These lines are caused successively to fall on the centre of the

slit by moving the card D, which for the nonce is covered with a piece

of ground glass, and the position of the shadow of the needle-point on

the scale is registered for each. A further check can be made by taking

a photograph of these lines, or of the solar spectrum, and having fixed

accurately on the scale any one of these lines already named, the

position of the others on the scale may be ascertained by measurement

from the photograph. Now the wave-lengths of these bright lines have

been most accurately ascertained, in fact as accurately as the dark

lines in the solar spectrum. Thus the scale on the card is a means of

localizing the colour passing through the slit or slits. Should more

than one slit be used in the spectrum the positions of each can be

determined in exactly the same way. The most tedious part of the whole

experimental arrangement with this apparatus is what may be called the

scaling of the spectrum.

A fairly large spectrum may be formed upon the screen without altering

any arrangement of the apparatus, when it has been adjusted to form

colour patches. If a lens L6 (see Fig. 6) of short focus be placed in

front of L4 (the big combining lens), an enlarged spectrum will be

thrown upon the screen F, and if slits be placed in the spectrum the

images of their apertures are formed by the respective coloured rays

passing through them, so that the colours which are combined in the

patch can be immediately seen.

Colour Measurement and Mixture · 第 4 / 16 章