CHAPTER II. CELLS AND BATTERIES.

Sources of Current. One of the chief difficulties of the average young

experimenter is to secure a satisfactory source of current for operating

his apparatus.

There are three means at his disposal and he may draw his electricity

from

1. A power or lighting circuit;

2. A dynamo;

3. Batteries.

[Illustration: FIG. 26.—A Voltaic Cell. A Voltaic Cell consists of a

Strip of Copper and a Strip of Zinc immersed in a dilute solution of

Sulphuric Acid.]

Only those who are so fortunate as to live in a house wired for light

and power service and supplied from the street mains, are likely to be

able to utilize the first named. Those experimenters who live in towns

where there are no commercial power wires or whose homes are not wired

for such service will have to therefore depend upon a dynamo or a

battery.

A dynamo is a very satisfactory source of current, provided some sort of

power, such as a windmill, water motor or small engine is available for

driving it. A hand dynamo is unsatisfactory for some purposes because

the experimenter is usually unable to drive the dynamo and attend to

other work at the same time.

Batteries are the most expensive source of current but for many reasons,

as explained above, are all that is available to the average

experimenter.

There are two classes of batteries, known as

1. Primary batteries;

2. Secondary or storage batteries.

*Primary Batteries* are those which generate their own current by the

action of some chemical such as, for example, an acid upon a metal.

*Secondary Batteries* derive their current from a dynamo or other source

of electricity and store it away in the form of *Chemical energy* until

it is used up. A storage battery might be likened to a pail, which can

be carried to a dynamo and filled full of electricity. Those who possess

a storage battery can recharge it themselves from the 110-volt lighting

or power circuit, from a dynamo or by taking it to an automobile garage

where recharging is done.

Homemade batteries are not as practical as those which can be purchased

ready made, but the knowledge and experience gained in making your own

are so valuable that every experimenter is urged to start in this way.

Various materials such as zinc, copper, carbon, etc., can be used to

make some very interesting and valuable batteries.

One of the most common mistakes made in reference to cells and batters

is in calling a single cell a *battery*. One cell is a cell. More than

one cell connected together is a *battery of cells* or simply a

*battery*.

The Voltaic Cell.

The first practical cell was invented in 1786 by an Italian professor

named Volta and it is, therefore usually called the Voltaic cell.

A Voltaic cell may be easily made by the experimenter, by placing some

water, mixed with sulphuric acid, in a glass tumbler or a jelly jar and

then immersing therein a strip of zinc and a strip of copper, each about

four inches long and one inch wide. The strips must be kept separate

from one another and should be scraped clean and bright before they are

placed in the solution. A copper wire is fastened to the top of each one

of the strips. The acid solution should be composed of one part of acid,

mixed with ten parts of water.

When mixing acid and water, always remember to pour the acid into the

water and never pour water into acid. Otherwise the solution will

suddenly become very hot and is liable to crack the jar. Acid should

always be mixed in a glass or earthenware vessel and never in any sort

of a wooden or metal receptacle, because it will attack and dissolve

metals and wood.

As soon as the acid has been prepared for the Voltaic cell fill a

tumbler about three quarters full and then immerse the zinc and copper

strips therein. As soon as the strips are in the acid, bubbles will

commence to rise from the zinc. These bubbles are a gas called hydrogen

and are evidence of a chemical action which takes place in a battery.

The zinc is being dissolved by the acid and during the process, sets

free hydrogen gas.

It will probably be noticed that very few bubbles arise from the copper

plate and that there seems to be little chemical action there.

It will also be noticed that if the two wires connected to the strips

are brought together the bubbles will arise from the zinc much faster

than before. That is because, when the wires are connected together, a

complete electrical circuit is formed: The zinc is really being oxidized

or slowly burned. If zinc is burned in the open air or in a fire it will

give out its energy in the form of heat but when it is burned in an acid

solution in the presence of another metal it gives out its energy in the

form of electricity.

The zinc strip in a Voltaic battery is known as the *negative* pole or

cathode, and the copper strip, as the positive pole or anode. When the

electrical circuit is completed by touching the two wires connected to

the poles together, the current is supposed to flow from the positive

pole through the wires and back into the solution through the negative

pole.

If the two wires, instead of being connected together, are connected to

an electrical instrument called a voltmeter the needle or pointer on the

meter will swing over and point to about one volt.

*A Voltmeter* is an instrument for measuring electrical pressure or

*potential*. The pressure of an electric current is measured in *volts*

just as the pressure of water may be measured in *pounds*.

If the copper strip is lifted out of the solution and a carbon plate or

rod also having a wire attached is substituted in its place it will be

found that the voltage or potential has increased to one and one-half

volts. Zinc and carbon are said to have a greater potential difference

than zinc and copper and inasmuch as it is usually desirable for a

battery to have the greatest potential difference possible, zinc and

carbon are employed in the batteries of to-day instead of zinc and

copper.

If the wires are then disconnected from the voltmeter and connected to

an electrical instrument called an *ammeter*, the needle or pointer will

probably swing over until it indicates a current of perhaps ten amperes.

An *ammeter* is an instrument for measuring the volume of an electric

current. An *ampere* is a unit of current and is used to designate the

rate of flow just as feet per second are used to denote rate of flow in

the case of water in a pipe.

If the meter is allowed to remain connected to the cell for a short time

it will be noticed that the pointer will commence to slowly drop back

towards zero.

The cell is then becoming *polarized*, which is to say that small

bubbles of hydrogen which are liberated by the chemical action, collect

on the carbon and cause the strength of the battery to fall off. If the

battery is agitated or the carbon is lifted out and scraped it will be

found that the current will immediately rise again to its first

strength.

It would be a nuisance if it were continually necessary to scrape the

carbon or shake the battery so as to avoid *polarization* and so another

means is employed to secure the desired result.

This is accomplished by introducing certain chemicals into the solution

which will give forth *oxygen*. When oxygen and hydrogen meet under

proper conditions they combine and form ordinary *water*.

*Bichromate of potash* or as it is also often called *potassium

bichromate* is the chemical most commonly employed for this purpose.

[Illustration: FIG. 27.—Ordinary Jelly Glasses, Tumblers, Fruit Jars,

etc, make good Jars for small cells by cutting off the tops.]

Homemade Batteries.

*The materials* required for making batteries, suitable as a source of

current for the experimenter, will not be found expensive in most cases.

*Carbon rods* and *plates* may be purchased from an electrical supply

house but they can also be easily and cheaply obtained from old dry

cells. Dry cells may be split open with a cold chisel and a hammer. Care

should be exercised not to break the carbon in removing it.

The round carbon rods used in arc lamps may be used for making batteries

provided that if they are copper plated, the copper is first removed by

immersing the rod in a bath of nitric acid. If this precaution is not

taken there will be a "local action" set up between the copper and the

carbon and the battery will not be as efficient as it will be if the

copper is removed.

Carbon rods and plates are easily drilled with an ordinary hand drill.

Carbon is quite brittle and breaks easily, therefore only very light

pressure should be used.

While zinc rods and plates may also be purchased they are easily made by

the experimenter who possesses a little ingenuity. The melting point of

zinc is quite low. It can be melted in a small iron pot and cast into

the form of rods or plates in plaster-of-Paris moulds. Plates may also

be cut out of heavy sheet zinc.

[Illustration: FIG. 28.—A Simple Home-made Cell.]

Ordinary jelly-glasses, tumblers, fruit jars, etc., make good jars for

small cells. The tops of fruit jars and batteries can be cut off so as

to make the opening larger.

The cutting can be done with an ordinary glass cutter or by filling a

scratch completely around the jar or bottle, at the place it is desired

to cut it off, with a three cornered file. If a hot poker or wire is

then held against the scratch it will commence to crack along the line

and follow the hot poker as it is drawn around.

[Illustration: FIG. 29.—A Home-made Battery having two Carbon Plates

with a Zinc Rod between.]

Figure 28 shows a simple arrangement consisting of a carbon and a zinc

plate mounted upon a wooden strip. The strip is used to support the

plates and rests across the top of the jar so that the plates hang below

in the solution. Most chemicals attack wood and for that reason it is

well to dip the strip in some hot paraffin. The carbon and zinc plates

are fastened on opposite sides of the wooden strip by means of a round

headed screw and a washer. A wire lead should be placed under the washer

on each plate. If the screw and washer are then smeared with some hot

paraffin or vaseline they will be protected from corrosion.

Care should be used so that the two screws employed to fasten the plates

to the strip do not touch each other in the wood. If they should, the

battery will be "short circuited" and the current will flow through the

screws instead of the wires.

Figure 29 shows an arrangement consisting of two carbon plates mounted

upon a wooden strip. The zinc element consists of a rod set in a whole

in the strip between the two carbon plates.

It will be found that two carbon plates will form a better cell than one

with only one plate or rod.

The arrangement illustrated in Figure 30 shows two carbon rods and one

zinc rod clamped between two wooden strips. The zinc rod is placed in

the center and the carbons to either side.

[Illustration: FIG. 30.—The Elements for a Simple Home-made Cell

composed of two Carbon Rods and one Zinc Rod clamped between two Wooden

Strips.]

The wooden strips are cut away a bit at the points where they clamp the

rods so as to form sort of a groove into which the rods fit without

slipping or twisting. The strips are drawn together tightly at the ends

by two wood screws.

When more than one carbon rod or plate is used in a cell, the carbons

should all be connected together so as to form a single unit.

The drawing in Figure 30 shows a wire twisted around the carbons so as

to connect them together but it would be a far better connection if the

wire was clamped between the carbons and the wood so that it is held

firmly.

Four carbon rods may be utilized by following the suggestion shown by

the drawing in Figure 31.

This consists of a square piece of wood about 4 x 4 inches and one-half

of an inch thick.

[Illustration: FIG. 31.—Four Carbon Rods and one Zinc Rod arranged to

form the Elements of a Cell.]

A zinc rod is set in a hole in the center. Four carbon rods are set in a

circle around the zinc and held in place by screws. All the carbon rods

should be connected together. The wooden top not only serves to support

the carbon and zinc rods, but will also act as a cover for the cell and

prevent the solution from evaporating.

Battery Solutions or Electrolytes.

It has already been shown how cells become "polarized" when the solution

consists simply of sulphuric acid and water. An ordinary acid solution

also has the further disadvantage that the zinc element is continually

consumed by the acid when it is in the solution, regardless of whether

current is being drawn from the cell or not. It is of course consumed

more rapidly when the circuit is complete and current is flowing than

when it is not, but the action is still nevertheless sufficiently rapid

to entirely consume the zinc even in the latter case in a very short

time. If an ordinary acid solution is used therefore as the liquid or

*electrolyte*, as it is technically termed, it is always necessary to

lift the elements out of their solutions whenever the cells are not in

use. They should be lifted out and carefully washed so as to remove all

traces of acid.

[Illustration: FIG. 32.—A Battery of Three Cells arranged so that they

can all be lifted out of the solution at once.]

A milder chemical which does not attack the zinc so rapidly as an acid

is often used wherever a battery is to be employed for ringing bells,

operating sounders, telephoning, etc., and only a small amount is

required.

Sal-ammoniac or chloride of ammonium, as it is also called, is a good

chemical for this purpose. It is very cheap and only requires to be

dissolved in water. A good strong solution should be made and an element

consisting of several carbons and one zinc such as those shown in

Figures 29, 30 and 31 used.

Such a cell will give about 1.5 volts and 3 or 4 amperes. If the current

is drawn from the battery continuously or too rapidly, it will also

*polarize* and the current will begin to fall off. The advantage of a

sal-ammoniac cell is that the elements may be left in the solution when

the cell is not in use, without appreciable waste of the zinc.

A very powerful cell of the non-polarizing type capable of delivering a

heavy current and having an E. M. F. of two volts can be made by adding

some potassium bichromate to a sulphuric acid solution.

An electrolyte of this sort may be prepared by dissolving four ounces of

bichromate of potash in sixteen ounces of water. Add to this, four

ounces of sulphuric acid. The acid should be added slowly and the

solution stirred at the same time.

This solution will be found an excellent one to use with cells having

carbon and zinc elements. The current and voltage are much higher than

those of an ordinary acid solution.

This type of cell also has the disadvantage that the zincs waste away

rapidly when in the solution, regardless of whether current is being

drawn or not. This can be partly overcome by *amalgamating* the zincs

with mercury. In order to amalgamate your battery zincs, procure a

little *mercuric nitrate* from a druggist or chemical house. Dissolve

the mercuric nitrate in a small amount of water and then rub the zincs

with a wad of cotton or cloth which has been dipped in the mercuric

nitrate solution.

The arrangement shown in Figure 32 is a very convenient one to follow in

arranging a battery of three or more cells. The elements of three cells

are all mounted upon a strip of paraffined wood and connected in series.

The three battery jars are placed in a row so that each pair of elements

will dip into their proper jar when the strip is laid across the tops.

Such an arrangement is not only more compact than one having the

elements composing each cell mounted upon separate strips, but will be

found very convenient when an electrolyte composed of bichromate of

potash and acid is used, because all the elements may then be raised out

of the solutions at the same time.

It is possible to place the jars in a frame and arrange a windlass

fitted with a crank so that the elements may be easily raised or lowered

from and to the solution. Such an arrangement is called a "plunge

battery."

Connecting Cells.

Cells may be connected either in *series*, in *multiple*, or in

*series-multiple*, depending upon the number of cells to be used and the

amperage and voltage desired.

[Illustration: FIG. 33.—Showing how Cells are arranged when they are

connected in Series. The Voltage of Six Dry Cells connected in series as

above would be approximately 6 x 1.5 or 9 Volts.]

Cells are in series when they are connected with a wire leading from the

negative pole of one of the positive pole of another, so that the

current flows through each one in turn. Figure 33 shows six cells

connected in series. Cells are placed in series when voltage is the most

important factor. The total voltage of the battery is then equal to the

sum of the voltages of the cells. For example, the voltage of the

ordinary dry cell is about 1.5 and therefore if four dry cells are

connected in series the total voltage of the battery will be six. If six

dry cells are connected in series the voltage at the terminals will be

about nine.

When a heavy amperage is desired, cells are connected in multiple.

Figure 34 shows six cells connected in multiple. It will be noticed that

all the negative poles are connected together to form one terminal,

while all the positive poles form another. The amperage of the average

dry cell is about 20. The amperage of a battery of cells connected in

multiple is equal to the sum of the amperages of the separate cells. The

amperage of four cells connected in multiple will be about 80 and about

120 in the case of six cells.

[Illustration: FIG. 34.—Showing Six Dry Cells connected in Multiple. The

Voltage of such an arrangement would only be 1.5, but the Amperage

available would be six times that possible from Cells connected as in

Figure 33.]

The life of the average dry cell is about twenty ampere hours under

normal conditions. If however the cell is discharged at a high rate, say

for instance, five amperes, it will be found that the life is less than

twenty ampere hours. On the other hand, if the discharge rate is very

low, as for example, one-quarter of an ampere, the capacity of the cell

will be greater. In order to get the most economical service from a

battery it is therefore advisable to lighten the load as far as

possible, and cells are consequently often connected in

*series-multiple* with that result in view. In a case, for illustration,

where it might be desirable to secure a current 4 1/2 volts and five

amperes from dry cells, the series-multiple arrangement could be

recommended. Three dry cells connected in series will furnish 4 1/2

volts and five amperes, but by using two sets as in Figure 35, the load

is divided between them and each set will only have to furnish amperes

to the circuit. *Two sets of cells used in series-multiple will

therefore last more than twice as long as either set would alone.*

The series-multiple arrangement is recommended where cells are to be

used for operating toy trains, induction coils, motors, etc., as being

the most economical.

Always be sure to use large wire in connecting cells. Fine wire offers

considerable resistance to the electrical current and the full benefit

of the batteries cannot be secured when it is used.

[Illustration: FIG. 35.—Showing how to connect a Battery of Cells in

Series-Multiple.]

Use care to scrape all connections so that they are clean and bright.

Tighten the binding posts with a pair of pliers so that there is no

chance of their becoming loose.

Another wise precaution is to always arrange batteries so that there is

a small space between two cells and no likelihood of any of the wires or

binding posts coming into contact with one another so as to form a short

circuit.

After the connections have been carefully made a little vaseline smeared

over them will prevent corrosion.

[Illustration: FIG. 36.—Battery Connectors like that shown above can be

obtained for 1 1/2 cents each and will be found to be very handy.]

Storage or Secondary Cells.

Storage or secondary cells (also sometimes called accumulators), differs

from primary cells in that they will not give forth an electric current

until they have been *charged* by passing an electric current through

them.

[Illustration: FIG. 37.—A Simple Experimental Storage Battery consisting

of two Lead Plates immersed in Dilute Sulphuric Acid.]

The Storage Cell is therefore a very convenient means of taking electric

energy at one time or place and storing it up for future use. From this

it must not be implied that electricity is actually stored in such a

battery. The energy of the electric current is really changed into

chemical energy and this energy produces electricity when the cell is

again discharged.

The superiority of the storage cell over any other form of battery is

universally recognized. The dry cell has an E. M. F. of only 1.5 volts

and deteriorates rapidly with age. The E. M. F. of a storage cell is 2

volts, or 33 1/3 per cent higher. Storage cells will operate almost any

electrical device with increased power over any other form of battery. A

wireless set will send farther, lamps will turn steadier and a motor

will give more power.

[Illustration: FIG. 38.—Showing how to charge a Simple Storage Cell

composed of two Lead Plates immersed in Sulphuric Acid by connecting it

to two Bichromate of Potash Cells.]

If properly cared for, a storage cell will last indefinitely. It may be

recharged an unlimited number of times and is exactly as good as new

each time. A dry cell must be thrown away when discharged.

Storage cells are rated by their output in *Ampere Hours.* An *Ampere

Hour* is the amount of current represented by one ampere flowing for one

hour. A 10 ampere hour cell will give 2 amperes for five hours, 1 ampere

for 10 hours, 1/2 ampere for 20 hours, etc. The ampere hour capacity of

a cell divided by the amount of current being used will determine how

long that current can be drawn before recharging is necessary.

Storage cells may be recharged from any source of *direct* current, that

is, from the lighting circuit, in series with a lamp, from a small shunt

wound dynamo, from dry cells or other primary batteries, or from

alternating current by using a *Rectifier*.

An Experimental Storage Cell.

Storage cells consist of lead plates immersed in an electrolyte of

dilute sulphuric acid.

Cut two strips, one inch wide and five inches long, out of sheet lead

about one-eighth of an inch thick.

Attach a wire to each one of the plates and then immerse them in a jar

full of *electrolyte* composed of:

1. Ten parts of water.

2. One part of sulphuric acid.

Connect the wire leading from the plates to a voltmeter and you will

notice that the pointer will not move away from zero.

Disconnect the wires and mark one plate as the *positive*, by means of a

little cross; mark the other plate *negative*, with a straight line.

Connect two good bichromate cells in series and lead the positive

terminal to the lead plate marked with a cross. Connect the negative

pole of the battery to the other lead plate. Bubbles of gas will

immediately begin to arise from the lead plates. Let the batteries

remain connected for about five minutes and then remove them. If you

then connect the two lead plates to the voltmeter again you will find

that the needle now swings nearly to two volts.

You will also find that your storage cell, for the two lead plates are

now a storage cell, will also ring a bell or run a small motor for a few

seconds.

The two lead plates became *charged* when the current from the

bichromate cells was passed through them. This little experiment

illustrates the principle of the storage cell very well.

A storage cell made of lead plates in the manner just described would

not possess sufficient capacity to make it worth while as a practical

cell. It has been found that if instead of a solid flat plate, a

framework or grid is used, consisting of a set of bars crossing one

another at right angles, leaving spaces between, which are filled with a

paste made of lead oxides, there will be a considerable gain in the

capacity of the cell.

A Homemade Storage Cell.

The storage cell illustrated in the accompanying illustrations is very

simple to make and a battery of them capable of delivering six or eight

volts will prove a very convenient source of current for performing all

sorts of electrical experiments.

[Illustration: FIG. 39.—Showing how the Plates for a Storage Cell may be

made from Sheet Lead by boring it full of holes and filling with paste.]

The plates are cut from sheet lead from one-quarter to five-sixteenths

of an inch thick. The height and width will depend upon the size of the

jars used. There are several sizes of rectangular glass storage cell

jars on the market, and if the plates are made about three inches wide

and three and one-half inches high, they will fit the smallest size of

jar. A lug about one inch and one-half long and three-quarters of an

inch wide is left projecting at the top.

Three plates are used in each cell. Each cell will have an E. M. F. of

two volts when fully charged. In order therefore to have a battery

capable of delivering six volts, three cells will be necessary. Nine

plates will be required for three cells.

The body of the plates should then be drilled full of holes about

one-eighth of an inch in diameter as shown by B in Figure 39.

The plates are now ready for pasting. Select three of the plates and

mark them with a small cross. These are to be *positive* plates when

finished. The paste for these plates is made by mixing red lead with

diluted sulphuric acid. The paste should form a good stiff mixture. Lay

the three plates upon a smooth board and press the paste carefully into

the holes with a flat stick. They are then laid aside to dry and harden.

[Illustration: FIG. 40.—A set of three Plates composed of One Positive

and Three Negatives assembled to form a Cell.]

The six remaining plates are to be *negatives* when finished and they

are pasted in identically the same manner as the positives except that

the paste is made of a mixture of yellow lead and dilute sulphuric acid

instead of red lead.

A pasted plate is shown at the right in Figure 39.

Cut six rectangular pieces, three by three and one-half inches, of heavy

blotting paper or thin whitewood. The thin wood used in the construction

of fruit baskets may be used for this purpose. These rectangles are to

be used as "separators" between the plates.

[Illustration: FIG. 41.—Glass and Rubber Storage Cell Jars which are on

the market for the Electrical Experimenter and may be purchased very

reasonably.]

The plates should then be assembled in groups of three, as shown in

Figure 40. The positive plate is placed in the centre with a separator

on either side. Two negative plates are then placed on the outside. The

lugs on the negative plates should come opposite to each other. A square

lead block having a hole bored through the centre may be placed between

the two negative lugs. The lugs are then clamped together with a binding

post and a screw. The plates are held in a compact bundle by two heavy

rubber bands passing around them.

Each group of plates is then placed in its proper jar and the jar filled

full of a mixture composed of:

1. Four parts of water, and

2. One part of sulphuric acid.

The plates are now ready for forming.

The cells are connected in series by leading a wire from the negative of

one to the positive of another and so on.

The terminals of the battery are then connected to a steady source of

direct current of at least ten volts. The positive pole of the battery

should be connected to the positive of the current source and the

negative to the negative.

The source of current may be (1) the 110 volt D. C. supply in series

with a lamp bank as described in Chapter IV; (2) the 110 volt A. C.

supply after it has passed through a rectifier; (3) another battery, or

(4) a shunt wound dynamo.

[Illustration: FIG. 42.—An empty Storage Cell Grid and also a Pasted

Plate both of which are on the market for experimenters who wish to

build their own Cells.]

The current passed through the storage cells during the forming process

should be about one ampere for cells of the size described above. As

soon as the positive plates of the storage cells have changed to a dark

chocolate-brown color and the negatives to a gray-slate, disconnect the

storage battery from the source of current and proceed to use it just as

you would any ordinary battery. Use it until it is exhausted and then

connect to the charging current again, taking care to make certain that

the positive pole of the battery is connected to the positive pole of

the current source.

After the cells have been recharged and discharged in this manner about

ten times they will be completely "formed" and ready for permanent

service.

Complete directions for recharging storage cells and instructions for

their care and maintenance will be found further on.

The only objection to the storage cells just described is that the paste

is liable to fall out of the plates in time. The plates or "grids" as

they are called used in commercial storage cells are cast in elaborate

moulds which make it possible to overcome this difficulty. Such grids

cannot however be made by the experimenter.

Jars, pasted plates and empty grids may be purchased from well known

firms dealing in apparatus for the experimenter, and with their aid it

is possible to construct a very substantial and durable storage cell at

home.

The empty grids or fully formed plates may be purchased in the following

sizes:

─────────────────────────────────────────────────────────────────

Positive or Negative Plate, size 2 7/8 x 2 1/2

─────────────────────────────────────────────────────────────────

" 3 1/8 x 2 7/8

─────────────────────────────────────────────────────────────────

" 3 5/8 x 5 3/4

─────────────────────────────────────────────────────────────────

" 4 3/4 x 2 7/8

─────────────────────────────────────────────────────────────────

" 4 3/4 x 5 3/4

─────────────────────────────────────────────────────────────────

Glass jars will be found satisfactory for stationary batteries. Rubber

jars are however advisable for portable batteries. Jars of the following

sizes may be easily obtained:

──────────────────────────────────────────────────────────────────

Glass Jar, outside 3 3/4 x 4 x 1 1/2 inches

──────────────────────────────────────────────────────────────────

Glass Jar, outside 3 3/4 x 5 x 1 1/2 inches

──────────────────────────────────────────────────────────────────

Hard Rubber Jar, outside. 6 1/2 x 3 1/2 x 1 1/2 inches

──────────────────────────────────────────────────────────────────

Hard Rubber Jar, outside. 6 1/2 x 6 1/2 x 1 1/2 inches

──────────────────────────────────────────────────────────────────

If the empty grids are purchased, they should be pasted in the same

manner as those plates just described. An empty grid of this type is

shown in Figure 42. A pasted plate is shown along side of it.

The two negative plates in cells of this type are fastened together by

"burning" into a lug, The lugs for this purpose may also be purchased

and will be found inexpensive.

The long lugs on the negative plates are cut off so that they will only

just project through the rectangular holes in the "connecting lug" when

the latter is in place, as shown by A in Figure 43.

The plates are "burned" into the connecting lug by using a red hot

soldering iron to melt the lead until they flow together at those

points. This is a job requiring a little skill and the experimenter had

better practice burning some odd bits of lead together first so as to

avoid all possibility of spoiling his plates.

[Illustration: FIG. 43.—Two Negative Plates "burned" together and the

Connecting Lug used.]

The positive plate is placed in position, as shown in Figure 44.

Wooden separators of the same size as the plates are placed between the

plates and the whole strapped together with heavy rubber bands near the

top and bottom.

The cells are then placed in their jars and the latter poured full of

electrolyte, providing that the batteries are to be of the stationary or

open type.

If it is desirable that they be portable and arranged so that the acid

will not easily spill, it will be necessary to seal them at the top.

The sealing is accomplished by cutting a "cover" strip out of thin wood

which will slip down over the lugs into the jar so that it comes about

one-half an inch below the top. A small hole should be bored in the

centre of the cover strip to receive a short piece of hard rubber or

lead tubing, which will act as a vent and permit the gases formed during

charging to escape or the electrolyte to be emptied at will.

[Illustration: FIG. 44.—The Elements of a Storage Cell composed of two

Negative Plates and one Positive Plate in their proper position.]

The cover strip should fit into the jar tightly so that when the sealing

mixture is poured in it will not run down around the plates or into the

jar.

The top of the battery is then poured full of a molten compound of

asphaltum and pitch.

No attempt should be made to seal the batteries when they contain acid.

The inside of the jar should be clean and dry.

After the cells are sealed and filled with electrolyte they are ready

for either forming or charging, depending upon whether the empty grids

were purchased and pasted by the experimenter or the plates were bought

already pasted and formed.

If they require forming, they must be put through the same forming

process which has already been described.

The finished cells when sealed will appear like those shown in Figure

45, according to the sizes of plates and jars used.

[Illustration: FIG. 45.—Three different sizes of Storage Cells which may

be purchased ready made or built by the experimenter out of prepared

materials as explained.]

Recharging and Caring for Storage Cells.

Storage cells are especially affected by the usage given them. If they

are mistreated they will quickly go to pieces, whereas, on the other

hand if well treated they will last indefinitely.

It is important that the electrolyte used in the cells should always be

of the proper strength. The only accurate method of preparing the

electrolyte is with the aid of a *hydrometer*. A hydrometer is an

instrument for determining the specific gravity of solutions.

It is a little device which looks somewhat like a thermometer. It is

placed in the solution and allowed to float. There is a numbered scale

along the upper part of the hydrometer and the *specific gravity* or

strength of the solution is indicated on the scale by the point which is

level with the surface of the solution.

The normal specific gravity for a storage battery solution should be

about 1.250. The strength can be increased by adding more acid and

decreased by adding water.

Ordinary commercial or technical grades of sulphuric acid and ordinary

water are satisfactory for primary batteries, but the acid and water

used in making the electrolyte for storage cells must be *chemically

pure* if you wish to obtain good results and desire your batteries to

hold their charge while standing.

Storage cells can be recharged with DIRECT current only. A dynamo for

recharging storage cells must be SHUNT wound. The voltage of the

charging current must be greater than that of the storage cells. About

three volts of charging current will be required for each cell of the

storage battery. Cells may be connected in multiple when recharging so

as to bring the voltage of the cells below that of the charging current.

It will of course, however, take much longer to recharge cells connected

in multiple than the same cells connected in series, provided that the

amperage of the current is the same.

Storage cells must not be recharged too rapidly. It is better to

recharge them slowly rather than too rapidly. Two amperes is plenty for

small cells of 10-15 ampere hours capacity. Three amperes is sufficient

for cells of 15-25 ampere hours capacity. Five to six amperes is the

right charging rate for a 40 ampere hour battery and 8 amperes in the

case of a 60 ampere hour battery.

[Illustration: FIG. 46.—A Hydrometer for preparing and testing the Acid

Solution for Storage Batteries.]

Storage cells should never be allowed to stand discharged for any length

of time or the plates are liable to become hardened and "sulphated."

They turn white when they are sulphated. It will take a great deal of

charging and recharging to get them back in shape when once they get in

that condition.

Never short circuit a storage cell or discharge it too rapidly.

Whenever any great amount of sediment collects in the bottom of the

jars, pour out the acid solution and wash the cell out thoroughly with

some pure water.

The plates of a storage cell should always be raised up off the bottom

of the jar, so that any sediment which collects will fall below.

[Illustration: FIG. 47.—The proper way of Recharging Storage Cells from

the 110 Volts D. C. Supply in series with a set of Lamps.]

It is a very good plan to keep the terminals of a storage cell or

battery smeared with vaseline so that they will not become corroded.

You can tell when a storage cell or battery is fully recharged by the

color of the plates. The positives will in that case be a dark chocolate

brown and the negatives a light slate gray color.

A cell which is fully recharged will indicate 2 1/2 volts on a voltmeter

connected across its terminals while the charging current is still on.

Home-made Electrical Apparatus · 第 2 / 19 章