ACIDUM TARTARICUM. L.

_Tartaric Acid._

QUALITIES. _Form_, Crystals of considerable size, whose primary form is

an oblique rhombic prism; they do not deliquesce when exposed to the

air, but melt at a heat a little exceeding 212°. _Taste_, very acid and

agreeable. SOLUBILITY. Water at 60° dissolves about one-fifth of its

weight, and when boiling, a much greater proportion. The solution,

which, if saturated, has the specific gravity 1·230, acquires, when

diluted, like that of most vegetable acids, a mouldy pellicle by

keeping. The saturating power of crystallized tartaric acid is almost

exactly equal to that of crystallized citric acid, the atomic weight of

the former being 76, and that of the latter 75. CHEMICAL COMPOSITION.

When uncombined with water, as it exists in tartrate of potass, it is

composed of 5 atoms of oxygen, 3 atoms of hydrogen, and 4 atoms of

carbon. The crystals consist of 1 atom of acid and 1 of water.

INCOMPATIBLE SUBSTANCES. Alkalies, Earths, and their carbonates; the

salts of lime and lead. The solutions of the salts of potass are

converted by it into bi-tartrate, or super-tartrate. MEDICINAL USES. It

is introduced into the Pharmacopœia as a cheap and efficient substitute

for the citric acid. It is also used in the preparation of _Sodaic

powders_, _Seidlitz powders_, &c. ADULTERATIONS. When carelessly

prepared it will contain sulphuric acid, to detect which, let a portion

be dissolved in distilled water, and a solution of acetate of lead be

added. A precipitate will appear which, if the acid be pure, will be

entirely redissolved by a few drops of acetic acid, or pure nitric acid.

If any portion remain undissolved, sulphuric acid is the cause. Muriate

of Baryta also, when sulphuric acid is present, but not otherwise, gives

a precipitate insoluble by an excess of muriatic acid.

Pharmacologia Fourth American, from the Seventh London Edition · 第 214 / 782 题