ON THE DEPOSITS OF EARTH WAX (OZOKERITE) IN EUROPE AND AMERICA.

[Footnote: Abstract from a paper read before the New York Academy of

Sciences.]

There exists a large mining and manufacturing industry in Austria, that

of ozokerite, or earth-wax, which has nothing like it in any other part

of the known world, an industry that supplies Europe with a part of its

beeswax, without the aid of the bees. It may not be generally known that

the mining of petroleum was a profitable industry in Austria long before

it was in this country. In 1852, a druggist near Tarnow distilled the

oil and had an exhibit of it in the first World's Fair in London.

In America, the first borings were made in 1859. Indeed, the use of

petroleum as an illuminator was common at a very early age in the

world's history. In Persia at Baku, in India on the Irawada, also in the

Crimea, and on the river Kuban in Russia, petroleum has been used

in lamps for thousands of years. At Baku the fire worshipers have a

never-ceasing flame, which has burned from time immemorial. The mines of

ozokerite are located in Austrian Poland, now known as Galicia. Near the

city of Drohabich, on the railway line running from Cracow to Lemberg,

is a town of six thousand inhabitants, called Borislau, which is

entirely supported by the ozokerite industry. It lies at the foot of

the Carpathian Mountains. About the year 1862, a shaft was sunk for

petroleum at that place. After descending about one hundred and eighty

feet, the miners found all the cracks in the clay or rock filled with

a brown substance, resembling beeswax. At first, the layers were not

thicker than writing paper; but they grew thicker gradually below, until

at a depth of three hundred feet they attained a thickness of three or

four inches. Upon examination, it was found that a yellow wax could be

made of a portion of this substance, and at once a substitute for wax

was manufactured.

The discovery caused an excitement like the oil fever of 1865 in

America. A large number of leases were made. When I saw the wells of

Pennsylvania, in 1879, there were more than two thousand. The owner

of the land received one-fourth of the product, and the miners

three-fourths. In the petroleum region, the leases at first were whole

farms, then they were reduced to 20, then 10, then 5, and at last to 1

acre, which is a square of 209 feet.

But in the ozokerite region of Poland, where everything is done on a

small scale, when compared with like enterprises in this country, the

leases were on tracts thirty-two feet square. These were so small that

the surface was not large enough to contain the earth that had to be

raised to sink the shaft; consequently the earth had to be transported

to a distance, and, when I saw it, there was a mound sixty or seventy

feet high. Its weight had become so great that it caused a sinking

of the earth, and endangered the shafts to such an extent that the

government ordered its removal to a distance and its deposit on ground

that was not undermined. The shafts are four feet square, and the sides

are supported by timbers six inches through, which leaves a shaft three

feet square. The miner digs the well or shaft just as we dig our water

wells, and the dirt and rock are hoisted up in a bucket by a rope and

windlass. But one man can work in the shaft at a time. For many years

no water was found; but, as there is a deposit of petroleum under the

ozokerite, at a depth of six hundred feet from the surface, the miners

were troubled with gas. This is got rid of by blowing a current of fresh

air from a rotary fan through a pipe extending down the shaft as fast as

the curbing of timber is put in place. The ozokerite is embedded in a

very stiff blue clay for a depth of several hundred feet; below, it is

interlaid with rock. [Specimens of crude and manufactured ozokerite were

on exhibition, through the kindness of Dr. J. S. Newberry.]

That part of the earth's surface has more miners' shafts to the acre

than any other part of the globe. As wages are very low in Poland,

averaging not more than forty cents a day for men and ten cents for

children, a very small quantity of ozokerite pays for the working. If

thirty or forty pounds a day is obtained, it remunerates the two men

and one or two children required to work each lease. When the bucket,

containing the earth, rock, and wax, is dumped in the little shed

covering the shaft, it is picked over by the children, who detach the

wax from the clay or rock with knives. The miners use galvanized wire

ropes and wooden buckets. When preparing to descend, they invariably

cross themselves and utter a short prayer. The business is not free from

danger, carelessness on the part of the boy supplying the fresh air, or

the caving in of the unsupported roof, causing a large number of deaths.

One of the government inspectors of the mines informed me that in one

week there had been eight deaths from accidents.

The ozokerite is taken to a crude furnace, and put into a common cast

iron kettle, and melted. This allows the dirt to sink to the bottom, and

the ozokerite, freed from all other solids, is skimmed off with a ladle,

poured into conical moulds, and allowed to cool, in which form it is

sold to the refiners, for about six cents per pound. The quantity

produced is uncertain, as the miners take care to understate it, for

the reason that the government lays a tax upon all incomes, and the

landowner demands his one-fourth of the quantity mined. The best

authority is Leo Strippelman, who states the quantity produced in

fifteen years at from 375,000,000 to 400,000,000 pounds, worth

twenty-four millions of dollars. As the owners of the land get

one-fourth of the sum, they received six millions. This is at the rate

of four hundred thousand a year, a rather valuable crop from some two

hundred acres of land.

The miners do not support the earth by timber or pillars, as they

should; the result is that the whole plot of about two hundred acres is

gradually sinking, and this will eventually ruin the industry in that

part of the deposit. In another part of the same field, a French company

has purchased forty acres, and it is mining the whole tract and hoisting

through one shaft by steam power. In that shaft they have sunk to a

depth of six hundred feet, and are troubled with water and petroleum.

These they pump out very much the same way as in coal and other mines,

worked in a scientific manner. The thickest layer of ozokerite found is

about eighteen inches, and this layer or pocket was a great curiosity.

When first removed at the bottom of the shaft, it was found to be so

soft that it was shoveled out like putty. During the night it oozed

into the space that had been emptied the day before; this continued for

weeks, or until the pressure of the gas had become too weak to force it

out.

I have been occupied in the petroleum region of Pennsylvania since 1860,

have seen all the wonderful development of the oil wells, and was very

much interested in contrasting the Austrian ozokerite and petroleum

industry with the American. It is a good illustration of the difference

between the lower class of Poles and Jews and the Yankee. Borislau,

after twenty years' work, was unimproved, dirty, squalid, and brutal. It

contained one school house, but no church nor printing office. None of

its streets were paved, and, in the main road through the town, the mud

came up to the hubs of the wagon wheels for over a mile of its length.

In places, plank had to be set up on edge to keep the mud out of the

houses, which were lower than the road. It contained numerous shops,

where potato whisky was sold to men, women, and children. It depends on

a dirty, muddy creek for its supply of water. Its houses were generally

one-story, built of logs and mud.

On the other hand, Oil City, a town of the same age and size, contained

eight school houses (one a high school building), twelve churches, and

two printing offices. It has paved streets, which, in 1863, were as deep

with mud as those in Borislau in 1879. It has no whisky shops where

women and children can drink. Many of its houses are of brick, two,

three, four, and five stories high. Its water works cost one hundred and

fifty thousand dollars. All this has been done since 1860, when it did

not contain forty houses.

I saw in the market place of Borislau women standing ankle deep in the

mud, selling vegetables. One woman really had to build a platform of

straw, on which to place a bushel of potatoes; if the straw foundation

had not been there, the potatoes would have sunk out of sight. Borislau

is three miles from Drohobich, a city of thirty thousand inhabitants;

between the two places, in wet weather, the road was impassable. For a

third of the way, it was in the bed of the creek; and I had to wait a

day for the water to fall so as to navigate it in a wagon. On inquiring

why they did not improve the road, I found the same difficulty as the

Arkansas settler encountered with his leaky roof; when it rained he

could not repair it, and when it was dry it did not need repair: so with

the road to Borislau.

Ozokerite (from the Greek words, "Ozein," to smell, and "Keros," wax) is

found in Turkistan, east of the Caspian Sea; in the Caucasian Mountains,

in Russia; in the Carpathian Mountains, in Austria; in the Apennines,

in Italy; in Texas, California, and in the Wahsatch Mountains, in the

United States. Commercially, it is not worked anywhere but in Austria;

although, I believe, we have in Utah a larger deposit than in any other

place. I made two journeys to examine the deposits in the Wahsatch

Mountains. For a distance of forty miles, it crops out in many places,

and on the Minnie Maud, a stream emptying into the Colorado, I found

a stratum of sand rock, from ten to twelve feet thick, filled with

ozokerite.

No systematic effort has been made to ascertain the quantity of

ozokerite in Utah. I saw a drift of some fourteen feet at one place, and

a shaft twenty-three feet deep at another. In this shaft, the vein was

about ten inches wide; and it could be traced along the slope of the

hill, for several hundred feet. The largest vein of pure ozokerite is

seen on Soldiers' Fork of Spanish Cañon, which enters Salt Lake Valley

near the town of Provo. This vein is very much like the ozokerite of

Austria, and contains between thirty and forty per cent. of white

ceresin (which resembles bleached beeswax), about thirty per cent. of

yellow ceresin (which resembles yellow wax), and twenty per cent. of

black petroleum; the residue is dirt. Dr. J. S. Newberry, of Columbia

College, and Prof. S. B. Newberry, of Cornell University, made

examinations of the ozokerite found in Utah; those who are interested

in the subject will find the papers published in the _Engineering and

Mining Journal_ for the year 1879.

A deposit of white ozokerite occurs on the top of the Apennine

Mountains, in Italy, of which a specimen is here exhibited. An

interesting story is told of its discovery. A church at Modena was

robbed; among other articles taken was a quantity of wax candles. A

short time afterward, a woman brought to a druggist a quantity of wax

and offered it for sale. The druggist bought it and afterward suspected

it consisted of the stolen candles melted down. Soon after ward she

brought another lot. He had her arrested. When questioned by the

magistrate, she said she found the wax in the clay on her farm, about

twenty miles from the city. This story confirmed him in the belief that

she had stolen the candles, or was the receiver of the stolen goods; for

such a thing as a deposit of wax in the soil was unheard of. She was

therefore remanded to jail. On three several days, she was brought

before the court, and, when questioned, told the same story. She was a

member of the church, and requested the priest to be sent for. He came,

and, after an interview between them, he said it was easy to disprove

her story, if it was a lie, by sending her home, in company with an

officer, to investigate. The court sent the priest, who was the only one

who believed her. On coming to her house, she took her pick and shovel,

and going to the place at the top of the hill, she dug out of the clay

a quantity of while ozokerite, proved her case, and was at once set at

liberty. She performed the same service for me, and I saw her dig the

specimen and heard her tell the story as I have told it to you. The hill

was composed of loose clay and stones. It appeared as if it had been

forced up by gas or some power from below the surface. The quantity that

could be gathered, by one person, laboring constantly for a week, was

only twenty-five or thirty pounds. An attempt had been made to sink a

shaft; but, at a depth of fourteen feet, the pressure of the clay was

sufficient to break the boards that held up the sides. The earth caved

in, and the shaft was abandoned.

It is not necessary here to describe the various processes of

manufacture; it will be sufficient to enumerate some of the forms of

ozokerite, and the uses to which it is put. At Borislau, there are

several refineries, where candles, tapers, and lubricating oils are

made. In Vienna, there are five factories; in one of these, they make

white wax, wax candles, matches, yellow beeswax, black heel-ball,

colored tapers, and crayon pencils. In Europe, large quantities of the

yellow wax are used to wax the floors of the houses, many of the finer

ones being waxed every day. It is a curious fact that the Catholic

Church does not allow the use of paraffine, sperm, or stearine candles;

at the same time nearly all the candles used in the churches in Europe

are made from ozokerite, which is a natural paraffine, made from

petroleum in nature's laboratory. In the United States, the only

uses made of ozokerite, so far as I know, are chewing gum and the

adulteration of beeswax. In this the Yankee gives another illustration

of the ruling passion strong in money making, which gives us wooden

nutmegs, wooden hams, shoddy cloth, glucose candy, chiccory coffee,

oleomargarine butter, mineral sperm oil made from petroleum, and beeswax

made without bees.

After this paper was written, the following translation from a pamphlet,

published by the First Hungarian Galician Railway Company, in 1879, came

to my notice. The writer's name is not published:

"Mineral wax, in the condition in which it is taken from the shafts,

is not well adapted for exportation, since it occurs with much earthy

matter; and, at any rate, an expensive packing in sacks would be

necessary. It is therefore first freed from all foreign substances by

melting, and cooled in conical cakes of about 25 kilos. weight, and

these cakes are exported. There are now, in Borislau, 25 melting works,

which, in 1877, with 1 steam and 60 fire kettles, produced 95,000 metric

centners (9,500,000 lb.).

"The melted earth wax is sent from Borislau to almost all European

countries, to be further refined. Outside of Austro-Hungary, we may

specially mention Germany, England, Italy, France, Belgium, and Russia

as large purchasers of this article of commerce.

"PRODUCTS AND THEIR APPLICATIONS.

"The products of mineral wax, are:

"(a.) _Ceresine_, also called ozocerotine or refined ozokerite, a

product which possesses a striking resemblance to ordinarily refined

beeswax. It replaces this in almost all its uses, and, by its cheapness,

is employed for many purposes for which beeswax is too dear. It is much

used for wax candles, for waxing floors, and for dressing linen and

colored papers. Wax crayons must be mentioned among these products. The

house of Offenheim & Ziffer, in Elbeteinitz, makes them of many colors.

These crayons are especially adapted to marking wood, stone, and iron;

also, for marking linen and paper, as well as for writing and drawing.

The writings and drawings made with these crayons can be effaced neither

by water, by acids, nor by rubbing.

"Concerning the technical process for the production of ceresine, it

should be said that, when the industry was new (the production of

ceresine has been known only about eight years, since 1874), it was

controlled by patents, which are kept secret. This much is known, that

the color and odor are removed by fuming sulphuric acid.

"From mineral wax of good quality about 70 per cent. of white ceresine

is obtained. The yellow ceresine is tinted by the addition of coloring

matter (annatto).

"(b.) _Paraffine_, a firm, white, translucent substance, without odor.

It is used, chiefly, in the manufacture of candles, and also as a

protection against the action of acids, and to make casks and other

wooden vessels water-tight, for coating corks, etc., for air-tight

wrappings, and, finally, for the preparation of tracing paper. There

are several methods of obtaining paraffine from ozokerite (see the

Encyclopedic Handbook of Chemistry, by Benno Karl and F. Strohmann, vol.

iv., Brunswick, 1877).

"The details of the technical process consists, in every case, in the

distillation of the crude material, pressure of the distillate by

hydraulic presses, melting, and treating by sulphuric acid.

"In the manufacture of paraffine from ozokerite, there are produced from

2 to 8 per cent. of benzine, from 15 to 20 per cent. of naphtha, 36

to 50 per cent. of paraffine, 15 to 20 per cent. of heavy oil for

lubricating, and 10 to 20 per cent. of coke, as a residue.

"(c.) _Mineral oils_, which are obtained at the same time with

paraffine, and are the same as those produced from crude petroleum,

described above. The process consists, as in the natural rock oils,

besides the distillation, in the treatment of the incidental products

with acids and alkalies.

"Of the products of ozokerite, manufactured in Galicia, the greater part

goes to Russia, Roumania, Turkey, Italy, and Upper Hungary. The common

paraffine candles made in Galicia--which are of various sizes, from

28 to 160 per kilo--are used by the Jews in all Galicia, Bukowuina,

Roumania, Upper Hungary, and Southern Russia, and form an important

article of commerce. Ceresine is exported to all the ports of the world.

Of late a considerable quantity is said to have been sent to the East

Indies, where it is used in the printing of cotton."

The President, Dr. J. S. Newberry, stated that ozokerite was undoubtedly

a product of petroleum. Little was known by the public concerning its

use and value. He exhibited specimens of natural brown ozokerite, of

yellow ozokerite, sold as beeswax, and of a white purified form, which

had been treated by sulphuric acid. Specimens from Utah had already been

shown before the Academy. There was no mystery as to its genesis in

either region, as it had been shown to be the result of inspissation of

a thick and viscid variety of petroleum. The term "petroleum" includes a

great variety of substances, from a limpid liquid, too light to burn,

to one that is thick and tarry. These differ widely also in chemical

composition: some yielding much asphalt by distillation, resembling a

solution of asphalt in turpentine; some containing so much paraffine

that a considerable quantity can be strained out in cold weather. The

asphalt in its natural form is a solid rock, to which the term "gum

beds" has been applied in Canada. These differences in constitution have

originated in the differences in the bituminous shales from which the

petroleum, ozokerite, etc., have been derived. In Canada, as excavations

are sunk through the asphalt, this becomes softer and softer, and

finally passes into petroleum. This is also the case in Utah.

* * * * *

[Concluded from SUPPLEMENT No. 400, page 6390.]

[KANSAS CITY REVIEW.]

Scientific American Supplement, No. 401, September 8, 1883 · 第 52 / 67 题